Organic Chemistry 9th Edition
ISBN: 9781305080485
Author: John E. McMurry
Publisher: John E. McMurry
1 Structure And Bonding 2 Polar Covalent Bonds; Acids And Bases 3 Organic Compounds: Alkanes And Their Stereochemistry 4 Organic Compounds: Cycloalkanes And Their Stereochemistry 5 Stereochemistry At Tetrahedral Centers 6 An Overview Of Organic Reactions 7 Alkenes: Structure And Reactivity 8 Alkenes: Reactions And Synthesis 9 Alkynes: An Introduction To Organic Synthesis 10 Organohalides 11 Reactions Of Alkyl Halides: Nucleophilic Substitutions And Eliminations 12 Structure Determination: Mass Spectrometry And Infrared Spectroscopy 13 Structure Determination: Nuclear Magnetic Resonance Spectroscopy 14 Conjugated Compounds And Ultraviolet Spectroscopy 15 Benzene And Aromaticity 16 Chemistry Of Benzene: Electrophilic Aromatic Substitution 17 Alcohols And Phenols 18 Ethers And Epoxides; Thiols And Sulfides 19 Aldehydes And Ketones: Nucleophilic Addition Reactions 20 Carboxylic Acids And Nitriles 21 Carboxylic Acid Derivatives: Nucleophilic Acyl Substitution Reactions 22 Carbonyl Alpha-substitution Reactions 23 Carbonyl Condensation Reactions 24 Amines And Heterocycles 25 Biomolecules: Carbohydrates 26 Biomolecules: Amino Acids, Peptides, And Proteins 27 Biomolecules: Lipids 28 Biomolecules: Nucleic Acids 29 The Organic Chemistry Of Metabolic Pathways 30 Orbitals And Organic Chemistry: Pericyclic Reactions 31 Synthetic Polymers Chapter19: Aldehydes And Ketones: Nucleophilic Addition Reactions
19.1 Naming Aldehydes And Ketones 19.2 Preparing Aldehydes And Ketones 19.3 Oxidation Of Aldehydes And Ketones 19.4 Nucleophilic Addition Reactions Of Aldehydes And Ketones 19.5 Nucleophilic Addition Of H2o: Hydration 19.6 Nucleophilic Addition Of Hcn: Cyanohydrin Formation 19.7 Nucleophilic Addition Of Hydride And Grignard Reagents: Alcohol Formation 19.8 Nucleophilic Addition Of Amines: Imine And Enamine Formation 19.9 Nucleophilic Addition Of Hydrazine: The Wolff–kishner Reaction 19.10 Nucleophilic Addition Of Alcohols: Acetal Formation 19.11 Nucleophilic Addition Of Phosphorus Ylides: The Wittig Reaction 19.12 Biological Reductions 19.13 Conjugate Nucleophilic Addition To A,b-unsaturated Aldehydes And Ketones 19.14 Spectroscopy Of Aldehydes And Ketones 19.SE Something Extra Section19.SE: Something Extra
Problem 27VC: Each of the following substances can be prepared by a nucleophilic addition reaction between an... Problem 28VC Problem 29VC Problem 30MP Problem 31MP Problem 32MP Problem 33MP Problem 34MP Problem 35MP Problem 36MP: It is not uncommon for organic chemists to prepare acetals by an exchange-type process known as... Problem 37MP Problem 38MP Problem 39MP Problem 40MP Problem 41MP: Aldehydes and ketones react with thiols to yield thioacetals just as they react with alcohols to... Problem 42MP Problem 43MP: When cyclohexanone is heated in the presence of a large amount of acetone cyanohydrin and a small... Problem 44MP Problem 45MP: The Meerwein-Ponndorf-Verley reaction involves reduction of a ketone by treatment with an excess of... Problem 46MP: Propose a mechanism to account for the formation of 3, 5-dimethyl- pyrazole from hydrazine and 2,... Problem 47MP Problem 48MP Problem 49MP: Treatment of an , -unsaturated ketone with basic aqueous hydrogen peroxide yields an epoxy ketone.... Problem 50MP Problem 51MP Problem 52MP Problem 53MP Problem 54AP Problem 55AP: Draw and name the seven aldehydes and ketones with the formula C5H10O. Which are chiral? Problem 56AP: Give IUPAC names for the following compounds: Problem 57AP: Draw structures of compounds that fit the following descriptions: a) An , unsaturated ketone, C9H8O... Problem 58AP: Predict the products of the reaction of (1) phenylacetaldehyde and (2) acetophenone with the... Problem 59AP: Show how you might use a Wittig reaction to prepare the following alkenes. Identify the alkyl halide... Problem 60AP: How would you use a Grignard reaction on an aldehyde or ketone to synthesize the following... Problem 61AP Problem 62AP Problem 63AP: How would you synthesize the following substances from benzaldehyde and any other reagents needed? Problem 64AP: Carvone is the major constituent of spearmint oil. What products would you expect from reaction of... Problem 65AP: How would you synthesize the following compounds from cyclohexanone? a) 1Methylcyclohexene b)... Problem 66AP: At what position would you expect to observe IR absorptions following molecules? Problem 67AP: Acidcatalyzed dehydration of 3hydroxy3phenylcyclohexanone leads to an unsaturated ketone. What... Problem 68AP: Choose the structure that best fits the IR spectrum shown. Problem 69AP: Propose structures for molecules that meet the following descriptions. Assume that the kinds of... Problem 70AP Problem 71AP Problem 72AP: When 4hydroxybutanal is treated with methanol in the presence of an acid catalyst,... Problem 73AP Problem 74AP Problem 75AP Problem 76AP Problem 77AP Problem 78AP: Tamoxifen is a drug used in the treatment of breast cancer. How would you prepare tamoxifen from... Problem 79AP: Compound A, MW 86, shows an IR absorption at 1730 cm-1 and a very simple 1H NMR spectrum with peaks... Problem 80AP: Compound B is isomeric with A (Problem 19-79) and shows an IR peak at 1715 cm-1. The 1H NMR spectrum... Problem 81AP: The 1HNMR spectrum shown is that of a compound with the formula C9H10O. How many double bonds and/or... Problem 82AP Problem 83AP: Propose structures for ketones or aldehydes that have the following 1H NMR spectra: (C9H10O2) IR:... Problem 84AP Problem 85AP Problem 86AP: The proton and carbon NMR spectra for each of three isomeric ketones with the formula C7H14O are... Problem 87AP: The proton NMR spectrum for a compound with formula C10H12O2 is shown below. The infrared spectrum... Problem 28VC
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When pent-2-yne reacts with mercuric sulfate in dilute sulfuric acid, the product is aketones. Give the structures of these products, and use mechanisms to
Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone
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