When looking down the C2-C3 bond of 2,3-dimethylbutane, what is the most stable conformer (A,B,C, D)? CH3 H. CH3 CH3 H3C. B A H' `CH3 H' `CH3 CH3 CH3 CH3 H3C, H3C CH3 C D -CH3 H CH3 CH3 CH3 H
When looking down the C2-C3 bond of 2,3-dimethylbutane, what is the most stable conformer (A,B,C, D)? CH3 H. CH3 CH3 H3C. B A H' `CH3 H' `CH3 CH3 CH3 CH3 H3C, H3C CH3 C D -CH3 H CH3 CH3 CH3 H
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:**Question:**
When looking down the C2–C3 bond of 2,3-dimethylbutane, what is the most stable conformer (A, B, C, or D)?
**Diagrams Explanation:**
The image shows four Newman projections labeled A, B, C, and D, depicting possible conformers of 2,3-dimethylbutane:
- **A:** The front carbon has one CH₃ group at the top and two H atoms at the sides. The back carbon has two CH₃ groups at the left and right, and one H atom at the bottom.
- **B:** The front carbon has two H atoms and one CH₃ group. The back carbon has one CH₃ group at the bottom and one at the right, with one H atom at the top.
- **C:** The front carbon is shown with CH₃ at the top and H at the bottom-left and right. The back carbon has CH₃ at the bottom-right and H at the left.
- **D:** The front carbon has one CH₃ group and two H atoms. The back carbon similarly has one CH₃ at the right and one at the bottom, with one H atom at the left.
**Key Points for Consideration:**
The most stable conformer usually minimizes steric hindrance, so the arrangement where larger groups (CH₃) are staggered and the distance between them is maximized will be preferred for stability reasons.
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