When Cr(CO)5(PH3) and Cr(CO)5(NH3) are oxidized by one electron: a. What is the change in LFSE? b. Does the C-O distance increase or decrease? Explain briefly. c. When Cr(CO)5(PH3) is oxidized, what is the effect on the Cr-P distance? Explain briefly. d. When Cr(CO)5(NH3) is oxidized, what is the effect on the Cr-N distance? Explain briefly. (T. Leyssens, D. Peeters, A. G. Orpen, J. N. Harvey, New J. Chem. , 2005 , 29 , 1424.)

When Cr(CO)5(PH3) and Cr(CO)5(NH3) are oxidized by one electron: a. What is the change in LFSE? b. Does the C-O distance increase or decrease? Explain briefly. c. When Cr(CO)5(PH3) is oxidized, what is the effect on the Cr-P distance? Explain briefly. d. When Cr(CO)5(NH3) is oxidized, what is the effect on the Cr-N distance? Explain briefly. (T. Leyssens, D. Peeters, A. G. Orpen, J. N. Harvey, New J. Chem. , 2005 , 29 , 1424.)

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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