When centrifugal stretching is included in the energy for the states of the rigid rotor, equation has an extra term nd 2B(J, + 1) - 4D(J, + 1), Equation (7- 67), where J is the quantum number for the initial rotational state, B is the rotational constant and D is the centrifugal distortion constant. Use the data in Table 7.2 to determine both B and D graphically. Be careful how you use units. Compare the magnitudes of B and D. What is the percent difference between B determined without centrifugal stretching and that found here including centrifugal stretching? What would be the corresponding percent error in the bond length computed from B?

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When centrifugal stretching is included in the energy for the states of the rigid rotor, equation has an extra term llind 2B(J, + 1) -4D(J, + 1), Equation (7-
67), where J is the quantum number for the initial rotational state, B is the rotational constant and D is the centrifugal distortion constant. Use the data in Table 7.2
to determine both B and D graphically. Be careful how you use units. Compare the magnitudes of B and D. What is the percent difference between B determined
without centrifugal stretching and that found here including centrifugal stretching? What would be the corresponding percent error in the bond length computed
from 8?
Transcribed Image Text:When centrifugal stretching is included in the energy for the states of the rigid rotor, equation has an extra term llind 2B(J, + 1) -4D(J, + 1), Equation (7- 67), where J is the quantum number for the initial rotational state, B is the rotational constant and D is the centrifugal distortion constant. Use the data in Table 7.2 to determine both B and D graphically. Be careful how you use units. Compare the magnitudes of B and D. What is the percent difference between B determined without centrifugal stretching and that found here including centrifugal stretching? What would be the corresponding percent error in the bond length computed from 8?
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