When 0.865 g sample of cyclohexane (molar mass = 84.16 g/mol) is burned in a bomb calorimeter, the temperature of the inner water bath and the calorimeter increases by 2.76 K. If DUө combustion of cyclohexane is - 3913 kJ/mol and the mass of the water in the inner bath is 1820 g, what is the calorimeter constant? Cp,m of water is 75.3 J K–1 mol–1. Recall that heat released by combustion is absorbed by both the inner water bath and the calorimeter.
Thermochemistry
Thermochemistry can be considered as a branch of thermodynamics that deals with the connections between warmth, work, and various types of energy, formed because of different synthetic and actual cycles. Thermochemistry describes the energy changes that occur as a result of reactions or chemical changes in a substance.
Exergonic Reaction
The term exergonic is derived from the Greek word in which ‘ergon’ means work and exergonic means ‘work outside’. Exergonic reactions releases work energy. Exergonic reactions are different from exothermic reactions, the one that releases only heat energy during the course of the reaction. So, exothermic reaction is one type of exergonic reaction. Exergonic reaction releases work energy in different forms like heat, light or sound. For example, a glow stick releases light making that an exergonic reaction and not an exothermic reaction since no heat is released. Even endothermic reactions at very high temperature are exergonic.
When 0.865 g sample of cyclohexane (molar mass = 84.16 g/mol) is burned in a bomb calorimeter, the temperature of the inner water bath and the calorimeter increases by 2.76 K. If DUө combustion of cyclohexane is - 3913 kJ/mol and the mass of the water in the inner bath is 1820 g, what is the calorimeter constant? Cp,m of water is 75.3 J K–1 mol–1.
Recall that heat released by combustion is absorbed by both the inner water bath and the calorimeter.
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