What is the major product(s) formed in the following reaction: A An equal mixture of 3 and 4 В An equal mixture of 1 and 2 C 2 is the major project D 3 is the major product E 4 is the major product Br NaSCN ? Heat SCN SCN 1) 2) 3)
Reactive Intermediates
In chemistry, reactive intermediates are termed as short-lived, highly reactive atoms with high energy. They rapidly transform into stable particles during a chemical reaction. In specific cases, by means of matrix isolation and at low-temperature reactive intermediates can be isolated.
Hydride Shift
A hydride shift is a rearrangement of a hydrogen atom in a carbocation that occurs to make the molecule more stable. In organic chemistry, rearrangement of the carbocation is very easily seen. This rearrangement can be because of the movement of a carbocation to attain stability in the compound. Such structural reorganization movement is called a shift within molecules. After the shifting of carbocation over the different carbon then they form structural isomers of the previous existing molecule.
Vinylic Carbocation
A carbocation where the positive charge is on the alkene carbon is known as the vinyl carbocation or vinyl cation. The empirical formula for vinyl cation is C2H3+. In the vinyl carbocation, the positive charge is on the carbon atom with the double bond therefore it is sp hybridized. It is known to be a part of various reactions, for example, electrophilic addition of alkynes and solvolysis as well. It plays the role of a reactive intermediate in these reactions.
Cycloheptatrienyl Cation
It is an aromatic carbocation having a general formula, [C7 H7]+. It is also known as the aromatic tropylium ion. Its name is derived from the molecule tropine, which is a seven membered carbon atom ring. Cycloheptatriene or tropylidene was first synthesized from tropine.
Stability of Vinyl Carbocation
Carbocations are positively charged carbon atoms. It is also known as a carbonium ion.
![H11.13 - Level 1
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What is the major product(s) formed in
the following reaction:
A
An equal mixture of 3 and 4
В
An equal mixture of 1 and 2
2 is the major project
3 is the major product
4 is the major product
Br
NaSCN
?
Heat
SCN
SCN
1)
2)
3)
4)](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fa0bb968a-5ec3-478b-b52a-55c42ca9d955%2F669d3c5d-d7ef-4f26-b192-a32bf57f6044%2Ft7uqau8_processed.jpeg&w=3840&q=75)
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