Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![The image provides instructions to draw the correct organic product for the reaction at -78 °C. The starting material is a molecule with a three-carbon chain featuring a terminal ketone group (a carbon double-bonded to an oxygen) with a chlorine atom attached to the third carbon.
The reaction is performed with the following reagents and conditions:
1. **Li⁺[AlH(OtBu)₃]⁻**
2. **H₂O**
The image also includes a drawing tool interface with options like "Select," "Draw," "Rings," "More," and "Erase." Drawing item options include single, double, and triple bonds, and elements such as carbon (C), hydrogen (H), oxygen (O), and chlorine (Cl).
### Explanation of Reagents
- **Li⁺[AlH(OtBu)₃]⁻**: This reagent is commonly used for selective reductions, often converting acyl chlorides to aldehydes.
- **H₂O**: Water is typically used to quench or neutralize the reaction.
This reaction diagram illustrates the conversion of the given acyl chloride to an aldehyde under the specified conditions. The ketone oxygen remains in the final product, typically resulting in an aldehyde at cold temperatures, as the reagent selectively reduces acyl chlorides without further reducing the product.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F67028db1-3c15-42d7-aa43-8659f6c3f0f2%2F89019067-d9b4-456e-a915-34f5f814b70a%2Fdbt64hr_processed.png&w=3840&q=75)
Transcribed Image Text:The image provides instructions to draw the correct organic product for the reaction at -78 °C. The starting material is a molecule with a three-carbon chain featuring a terminal ketone group (a carbon double-bonded to an oxygen) with a chlorine atom attached to the third carbon.
The reaction is performed with the following reagents and conditions:
1. **Li⁺[AlH(OtBu)₃]⁻**
2. **H₂O**
The image also includes a drawing tool interface with options like "Select," "Draw," "Rings," "More," and "Erase." Drawing item options include single, double, and triple bonds, and elements such as carbon (C), hydrogen (H), oxygen (O), and chlorine (Cl).
### Explanation of Reagents
- **Li⁺[AlH(OtBu)₃]⁻**: This reagent is commonly used for selective reductions, often converting acyl chlorides to aldehydes.
- **H₂O**: Water is typically used to quench or neutralize the reaction.
This reaction diagram illustrates the conversion of the given acyl chloride to an aldehyde under the specified conditions. The ketone oxygen remains in the final product, typically resulting in an aldehyde at cold temperatures, as the reagent selectively reduces acyl chlorides without further reducing the product.
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