Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![### Question 1
**What is the major product of the reaction below?**
The reaction involves a benzene molecule reacting with acetyl chloride in the presence of the catalyst AlCl₃ (Aluminum chloride), which is typical of the Friedel-Crafts acylation reaction. The products labeled A, B, C, and D are potential products of this reaction.
#### Reactants:
- **Benzene (C₆H₆)**
- **Acetyl chloride (CH₃COCl)**
#### Catalyst:
- **AlCl₃ (Aluminum chloride)**
#### Products:
- **A:** Contains two carbonyl functional groups attached to the benzene ring at the 1 and 4 positions (para position), indicating a diacetyl benzene.
- **B:** Contains two carbonyl functional groups attached to the benzene ring at the 1 and 3 positions (meta position), indicating another diacetyl benzene.
- **C:** Contains three carbonyl functional groups, with the groups located at the 1 and 4 positions of the first benzene ring and at the 3 position of the second benzene ring, forming a triacetyl benzene.
- **D:** Contains a single carbonyl functional group attached to the benzene ring at the 1 position, indicating a monoacetyl benzene.
**Options:**
- ○ A
- ○ B
- ○ C
- ○ D
Given the conditions of the reaction and the typical behavior of Friedel-Crafts acylation, the major product of this reaction is a monoacetyl benzene.
**Correct Answer:**
- ○ D](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F5bc418ab-5051-450d-ba5a-1e906e0fb9c9%2F37c5894d-aa3e-483a-b2fd-4f5450800456%2Flbgij2o_processed.jpeg&w=3840&q=75)
Transcribed Image Text:### Question 1
**What is the major product of the reaction below?**
The reaction involves a benzene molecule reacting with acetyl chloride in the presence of the catalyst AlCl₃ (Aluminum chloride), which is typical of the Friedel-Crafts acylation reaction. The products labeled A, B, C, and D are potential products of this reaction.
#### Reactants:
- **Benzene (C₆H₆)**
- **Acetyl chloride (CH₃COCl)**
#### Catalyst:
- **AlCl₃ (Aluminum chloride)**
#### Products:
- **A:** Contains two carbonyl functional groups attached to the benzene ring at the 1 and 4 positions (para position), indicating a diacetyl benzene.
- **B:** Contains two carbonyl functional groups attached to the benzene ring at the 1 and 3 positions (meta position), indicating another diacetyl benzene.
- **C:** Contains three carbonyl functional groups, with the groups located at the 1 and 4 positions of the first benzene ring and at the 3 position of the second benzene ring, forming a triacetyl benzene.
- **D:** Contains a single carbonyl functional group attached to the benzene ring at the 1 position, indicating a monoacetyl benzene.
**Options:**
- ○ A
- ○ B
- ○ C
- ○ D
Given the conditions of the reaction and the typical behavior of Friedel-Crafts acylation, the major product of this reaction is a monoacetyl benzene.
**Correct Answer:**
- ○ D
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