Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Question

Transcribed Image Text:**Title: Understanding Hydrolysis of Nitriles**
**Text:**
In this transformation, the given substrate is a nitrile compound. The reaction involves the conversion of this nitrile in the presence of hydrochloric acid (HCl) at a temperature of 40°C. This is an example of an acid-catalyzed hydrolysis reaction.
**Reaction Details:**
- **Reactant:** A four-carbon nitrile (butyronitrile), characterized by the presence of a cyano group (C≡N) attached to a propyl chain.
- **Reagent:** Hydrochloric acid (HCl).
- **Conditions:** A temperature of 40°C.
**Expected Outcome:**
Under the reaction conditions, the nitrile group will undergo hydrolysis, resulting in the formation of a carboxylic acid. The major product of this reaction is likely to be butyric acid. This occurs as the nitrile group converts to a carboxyl group (-COOH) through the intermediate formation of an amide, which further hydrolyzes to the acid.
**Conclusion:**
The acid-catalyzed hydrolysis of nitriles converts them into carboxylic acids under mild temperatures and acidic conditions. This reaction pathway is crucial in organic synthesis for producing carboxylic acids from nitriles.
Expert Solution

Step 1: Reaction scheme and type of reaction
The given reaction scheme is .
We have to give the major product of this reaction.
The given reaction is an example of acid catalysed nitrile hydrolysis reaction.
Step by step
Solved in 3 steps with 3 images
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