Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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what is the final and major product of the reaction shown below?
![The image depicts a chemical reaction involving an organic compound. The structure shown is a phenylacetylene, which consists of a benzene ring (phenyl group) attached to an acetylene group (C≡CH).
The reaction sequence is as follows:
1. Reagent: Disiamylborane
2. Reagents: Hydrogen peroxide (H₂O₂) and hydroxide ion (OH⁻)
The question mark indicates that the product of the reaction is to be determined.
### Explanation:
This sequence involves hydroboration-oxidation of an alkyne. During the first step, disiamylborane adds across the carbon-carbon triple bond. This is followed by oxidation with hydrogen peroxide in the presence of a base (OH⁻) to yield an alcohol. In the case of terminal alkynes like phenylacetylene, this process typically results in an aldehyde product through tautomerization from the initial enol form.
### Conclusion:
The reaction transforms the phenylacetylene to an aldehyde with the phenyl group remaining attached.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fae1ff063-3271-4fde-815d-82e6dcfbb8e2%2Fb66ff49b-c8b1-4536-b862-3ed97b3eb53c%2F8iiucps_processed.jpeg&w=3840&q=75)
Transcribed Image Text:The image depicts a chemical reaction involving an organic compound. The structure shown is a phenylacetylene, which consists of a benzene ring (phenyl group) attached to an acetylene group (C≡CH).
The reaction sequence is as follows:
1. Reagent: Disiamylborane
2. Reagents: Hydrogen peroxide (H₂O₂) and hydroxide ion (OH⁻)
The question mark indicates that the product of the reaction is to be determined.
### Explanation:
This sequence involves hydroboration-oxidation of an alkyne. During the first step, disiamylborane adds across the carbon-carbon triple bond. This is followed by oxidation with hydrogen peroxide in the presence of a base (OH⁻) to yield an alcohol. In the case of terminal alkynes like phenylacetylene, this process typically results in an aldehyde product through tautomerization from the initial enol form.
### Conclusion:
The reaction transforms the phenylacetylene to an aldehyde with the phenyl group remaining attached.
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