Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter12: Atoms And Molecules
Section: Chapter Questions
Problem 12.12E: Are mathematical expressions for the following potential energies positive or negative? Explain why...
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Concept explainers
Atomic Structure
The basic structure of an atom is defined as the component-level of atomic structure of an atom. Precisely speaking an atom consists of three major subatomic particles which are protons, neutrons, and electrons. Many theories have been stated for explaining the structure of an atom.
Shape of the D Orbital
Shapes of orbitals are an approximate representation of boundaries in space for finding electrons occupied in that respective orbital. D orbitals are known to have a clover leaf shape or dumbbell inside where electrons can be found.
Question
Part A: What is the energy of the system when in its ground state, in units of eV?

Transcribed Image Text:### Quantum Mechanics: Particle in a Box
#### Diagram Description
The diagram illustrates a one-dimensional potential energy well (also known as an infinite potential well), which is represented by a box with infinitely high walls. The potential energy \( U \) is indicated by two vertical arrows pointing upwards at \( x = 0 \) and \( x = L \), suggesting infinite potential at these boundaries. The region between these points (from 0 to L on the x-axis) is where the particle, in this case, a neutron, is confined.
#### System Description
A neutron is trapped in a one-dimensional box of length \( L = 2.00 \times 10^{-11} \) meters, with walls of infinite potential energy. This means that the neutron cannot exist outside the defined region between the walls. The rest mass of the neutron is given as \( 1.68 \times 10^{-27} \) kilograms. Initially, the neutron is in its ground state configuration, which is its lowest energy state.
Upon interacting with a photon, the neutron absorbs energy and is excited to a higher energy level, specifically to the state \( n = 2 \). This process exemplifies quantum excitation, where the energy absorbed from the photon causes the neutron to "jump" to a higher energy state within its confined environment.
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