What is the electric potential (E) for the following redox reaction at 298K when [Ni²*] = 3.0 M, and [Zn**] = 0.1 M? Zn Zn2* Ni

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13. What is the electric potential (E) for the following redox reaction at 298K when [Ni²*] = 3.0 M,
and [Zn*] = 0.1 M?
Zn
Zn²*
Ni
Transcribed Image Text:13. What is the electric potential (E) for the following redox reaction at 298K when [Ni²*] = 3.0 M, and [Zn*] = 0.1 M? Zn Zn²* Ni
Half Reaction
Ered
3 e
Al
- 1.66 V
+
2 e
Br2
2 Br
+ 1.07 V
+
2 e
Co2+
- 0.28 V
+
Co
3 e
Cr
- 0.74 V
2 e
Cu²+
Cu
+ 0.34 V
2 e
F2
2 F
+ 2.87 V
+
2 e
Fe2+
Fe
- 0.44 V
e
Fe3+
Fe2+
+ 0.77 V
2 e
Mg?
Mg
- 2.37 V
+
2 e
Ni2+
Ni
- 0.28 V
2 e
Pb
- 0.13 V
2 e
Sn+
Sn2*
+ 0.15 V
2 e
Zn2+
Zn
- 0.76 V
+
+
+
Transcribed Image Text:Half Reaction Ered 3 e Al - 1.66 V + 2 e Br2 2 Br + 1.07 V + 2 e Co2+ - 0.28 V + Co 3 e Cr - 0.74 V 2 e Cu²+ Cu + 0.34 V 2 e F2 2 F + 2.87 V + 2 e Fe2+ Fe - 0.44 V e Fe3+ Fe2+ + 0.77 V 2 e Mg? Mg - 2.37 V + 2 e Ni2+ Ni - 0.28 V 2 e Pb - 0.13 V 2 e Sn+ Sn2* + 0.15 V 2 e Zn2+ Zn - 0.76 V + + +
Expert Solution
Step 1

The balanced reaction taking place is given as,

=> Zn + Ni2+ ---------> Ni + Zn2+ 

Given : [Ni2+ ] = 3.0 M

And [Zn2+ ] = 0.1 M

 

Step 2

In the above reaction, the oxidation state of Zn is increasing from 0 to 2 and Ni is decreasing from 2 to 0.

Hence the reduction of Ni and oxidation of Zn is taking place in the above reaction.

Hence the standard cell potential of the above reaction is given by,

=> Eocell = Ered - Eox 

where Ered = reduction potential of species being reduced = -0.28 V

And Eox = reduction potential of species being oxidised = -0.76 V

Hence Eocell = -0.28 - (-0.76) = 0.48 V

Also, in the above reaction, 1 Zn is gaining 2 electrons to become Zn2+.

Hence the number of electrons transferred in the reaction = n = 2.

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