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- Consider the galvanic cell based on the following half-reactions. Ag+ + e → Ag Cd²+ + 2e →→ Cd (a) Determine the overall cell reaction and calculate º chemPad XX² cell 8° = +0.80 V 8⁰ = -0.40 V V AGO K Help Greek (b) Calculate AGº (in kJ) and K for the cell reaction at 25°C. kJ (in V). (Use the lowest possible whole number coefficients. Omit states-of-matter from your answer.) cell (c) Calculate cell (in V) at 25°C when [Ag+ ] = V 1.0×10-4 M and [Cd²+] = 1.0×10-² M.A certain metal M forms a soluble sulfate salt M₂SO4. Suppose the left half cell of a galvanic cell apparatus is filled with a 2.00 M solution of M₂SO4 and the right half cell with a 10.0 mM solution of the same substance. Electrodes made M are dipped into both solutions and a voltmeter is connected between them. The temperature of the apparatus is held constant at 35.0 °C. Which electrode will be positive? What voltage will the voltmeter show? Assume its positive lead is connected to the positive electrode. Be sure your answer has a unit symbol, if necessary, and round it to 2 significant digits. V left right x10 X TCalculate the concentration of an unknown solution in a concentration cell. A concentration cell consisting of two hydrogen electrodes (P H2- latm), where the cathode is a standard hydrogen electrode and the anode solution has an unknown pH, has a cell voltage of 0.193 V. What is the pH in the unknown solution? Assume the temperature of the solutions is 298 K. !! pH =
- 3. Calculate the free energy, AG°, for each electrochemical cell given the following information and determine if the reaction is spontaneous or nonspontaneous. T= 298 K a. E cell =+ 2.10 V, n= 2 b. Каg— 2.2 х 10-3 c. E cell =- 0.677 V, n = 3 =Consider the following voltaic cellat 25°C: Al(s) | Al3*(0.20 M, aq) || Al3+(0.75 M, aq) | Al(s) If the standard reduction potential for the Al3+(aq) /Al(s) redox couple is -1.66 V, what is the overall cell reaction and the cell potential of the voltaic cell shown above? (Reference the cell as written above.) The overall cell reaction is Al3+(0.75 M, aq) AIS*(0.20 M, ag) and E°cell = +0.0113 V. There is no overall cell reaction and E°cell = 0.00 V. The overall cell reaction is Al3+(0.20 M, aq) Als*(0.75 M, aq) and E°cell = +0.0113 V. The overall cell reaction is Al3+(0.20 M, aq) →A13+(0.75 M, ag) and E°cell| = -0.0113 V. The overall cell reaction is Al3*(0.75 M, aq) →AI3*(0.20 M, aq) and E°cell = -0.0113 V. None of theseA certain half-reaction has a standard reduction potential Ered = -1.01 V. An engineer proposes using this half-reaction at the cathode of a galvanic cell that must provide at least 1.00 V of electrical power. The cell will operate under standard conditions. Note for advanced students: assume the engineer requires this half-reaction to happen at the cathode of the cell. Is there a minimum standard reduction potential that the half-reaction used at the anode of this cell can have? If so, check the "yes" box and calculate the minimum. Round your answer to 2 decimal places. If there is no lower limit, check the "no" box. Is there a maximum standard reduction potential that the half-reaction used at the anode of this cell can have? If so, check the "yes" box and calculate the maximum. Round your answer to 2 decimal places. If there is no upper limit, check the "no" box. By using the information in the ALEKS Data tab, write a balanced equation describing a half reaction that could be used…
- A certaln metal M forms a soluble nitrate salt M(NO,). Suppose the left half cell of a galvanic cell apparatus is filled with a 3.00 M solution of M(NO,). and the right half cell with a 3.00 mM solution of the same substance. Electrodes made of M are dipped into both solutions and a voltmeter is connected between them. The temperature of the apparatus is held constant at 25.0 °C. O left do Which electrode will be positive? x10 O right Ar What voltage will the voltmeter show? Assume its positive lead is connected to the positive electrode. Be sure your answer has a unit symbol, if necessary, and round it to 2 significant digits. Explanation Check 2021 McGraw-Hill Education. Ali Rights Reserved. Terms of Use | Privacy Accessibility O 3:08 hp esc ! #3 & backs 1 2 3 5 6. 7 8. 9. %24A certain metal M forms a soluble nitrate salt M (NO₂), Suppose the left half cell of a galvanic cell apparatus is filled with a 40.0 mM solution of M(NO), and the right half cell with a 4.00 M solution of the same substance. Electrodes made of M are dipped into both solutions and a voltmeter is connected between them. The temperature of the apparatus is held constant at 25.0 °C. Which electrode will be positive? What voltage will the voltmeter show? Assume its positive lead is connected to the positive electrode. Be sure your answer has a unit symbol, if necessary, and round it to 2 significant digits. O left O right 0 0.2 X Glo ArA certain metal M forms a soluble nitrate salt M(NO3). Suppose the left half cell of a galvanic cell apparatus is filled with a 4.00 M solution of M(NO3), and the right half cell with a 200. mM solution of the same substance. Electrodes made of M are dipped into both solutions and a voltmeter is connected between them. The temperature of the apparatus is held constant at 30.0 °C. Which electrode will be positive? What voltage will the voltmeter show? Assume its positive lead is connected to the positive electrode. Be sure your answer has a unit symbol, if necessary, and round it to 2 significant digits. left ☐ x10 right
- Consider the following galvanic cell: E° (V) U3+ + 3 e− → U(s) −1.642 In3+ + 2e− → In+ −0.444 What is the cathode? U/U3+ In3+/In+ Pt/In3+ Pt/In+Consider the following galvanic cell: E° (V) U3+ + 3 e− → U(s) −1.642 In3+ + 2e− → In+ −0.444 The electron flow is clockwise electrons don't move in this galvanic cell counterclockwisemass of an rolysis product from the applied... When a lead acid car battery is recharged by the alternator, it acts essentially as an electrolytic cell in which solid lead(II) sulfate (PbSO,) is reduced to lead at the cathode and oxidized to solid lead(II) oxide (PbO) at the anode. Suppose a current of 16.0 A is fed into a car battery for 47.0 seconds. Calculate the mass of lead deposited on the cathode of the battery. Be sure your answer has a unit symbol and the correct number of significant digits. Explanation Check O 2022 McGraw Hill LLC. All Rights Reserved. Terms of Use I Privacy Center o search 99+ DE