What is the boiling point of the azeotrope? If a liquid with Xamm=0.2 is heated, at what temperature does the first vapor appear? What is the composition of the first vapor?

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
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What is the boiling point of the azeotrope?

If a liquid with Xamm=0.2 is heated, at what temperature does the first vapor appear?

What is the composition of the first vapor?

The image features a graph that details the relationship between the temperature (T) and the molar concentration of ammonia (x, y - molar). The temperature is represented on the vertical axis and is scaled from 300 to 390 Kelvin, with 10 K intervals. The horizontal axis represents the molar concentration of ammonia, ranging from 0.0 to 1.0.

The graph includes two lines:

1. **Solid Line ("Experimental Data of Kay & Phink 1957")**: This line indicates the experimental data obtained from a study conducted by Kay & Phink, published in 1957.

2. **Dashed Line**: Represents theoretical or calculated data for reference, labeled as "PRP 1.0," "2.0," "3.0," "4.0," "5.0," indicating different models or versions.

There is an annotation pointing to a specific part of the graph labeled "point," suggesting a key area of interest or significant data point on the experimental curve.

The graph's data shows a trend where the temperature tends to decrease initially with an increase in ammonia concentration before leveling off. This could suggest a phase change or another chemical physical transition involving ammonia as the mole ratio increases.
Transcribed Image Text:The image features a graph that details the relationship between the temperature (T) and the molar concentration of ammonia (x, y - molar). The temperature is represented on the vertical axis and is scaled from 300 to 390 Kelvin, with 10 K intervals. The horizontal axis represents the molar concentration of ammonia, ranging from 0.0 to 1.0. The graph includes two lines: 1. **Solid Line ("Experimental Data of Kay & Phink 1957")**: This line indicates the experimental data obtained from a study conducted by Kay & Phink, published in 1957. 2. **Dashed Line**: Represents theoretical or calculated data for reference, labeled as "PRP 1.0," "2.0," "3.0," "4.0," "5.0," indicating different models or versions. There is an annotation pointing to a specific part of the graph labeled "point," suggesting a key area of interest or significant data point on the experimental curve. The graph's data shows a trend where the temperature tends to decrease initially with an increase in ammonia concentration before leveling off. This could suggest a phase change or another chemical physical transition involving ammonia as the mole ratio increases.
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