The following pertains to the study of aniron complex with structure as shownbelow. A cyclic voltammogram (CV) ofthe complex isshown at the right.The complexdesignated as 1 isthe 2+ ion, 2 is the 1+ion, and 3 is the2340x10Scan Rate (mVis)102550-72T1-20100200Ar-1, 88%Ar = 3,5-Me,Ph20 -2 €30.6-0.8-1.01.21.4-1.6-1.8-2.0neutral species. [Billups, J.; Fokakis, Z.;Creutz, S. Octahedral Iron Complexes of Pyrazine(diimine) Pincers: Ligand Electronic Effectsand Protonation. Inorg. Chem. 2020, 59, 15228-15239].Potential (V vs. Fc/Fc+)What are reversible and irreversible electrochemical processes? How do they appear in acyclic voltammogram? Indicate on the CV whether the processes observed are reversibleor irreversible.Current (A) d. Using the reduction potentials evident in the CV above, calculate the K. for the series ofcomplex ions [(+-OM²P²DI),Fe]* and then compare it to the K. value for a similar series ofcomplexes of formula [(+-OM PDI)2Fe]a+ which has a AE=0.35V. (AE=RT InK/nF)

Cyclic voltammetry is an important tool to analysis redox characteristics of an electrochemical…

Answered: What are reversible and irreversible…

What are reversible and irreversible electrochemical processes? How do they appear in a cyclic voltammogram? Indicate on the CV whether the processes observed are reversible or irreversible.

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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