The following pertains to the study of aniron complex with structure as shownbelow. A cyclic voltammogram (CV) ofthe complex isshown at the right.The complexdesignated as 1 isthe 2+ ion, 2 is the 1+ion, and 3 is the2340x10Scan Rate (mVis)102550-72T1-20100200Ar-1, 88%Ar = 3,5-Me,Ph20 -2 €30.6-0.8-1.01.21.4-1.6-1.8-2.0neutral species. [Billups, J.; Fokakis, Z.;Creutz, S. Octahedral Iron Complexes of Pyrazine(diimine) Pincers: Ligand Electronic Effectsand Protonation. Inorg. Chem. 2020, 59, 15228-15239].Potential (V vs. Fc/Fc+)What are reversible and irreversible electrochemical processes? How do they appear in acyclic voltammogram? Indicate on the CV whether the processes observed are reversibleor irreversible.Current (A) d. Using the reduction potentials evident in the CV above, calculate the K. for the series ofcomplex ions [(+-OM²P²DI),Fe]* and then compare it to the K. value for a similar series ofcomplexes of formula [(+-OM PDI)2Fe]a+ which has a AE=0.35V. (AE=RT InK/nF)

Cyclic voltammetry is an important tool to analysis redox characteristics of an electrochemical…

Answered: What are reversible and irreversible…

What are reversible and irreversible electrochemical processes? How do they appear in a cyclic voltammogram? Indicate on the CV whether the processes observed are reversible or irreversible.

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Report all answers with the proper number of significant figures. In an electrolysis experiment similar to the one employed this experiment; a student observed that his unknown metal anode lost 0.238 grams while a total volume of 94.50 mL of hydrogen was being produced. The temperature of the solution was 25oC and the barometric pressure was 739 mm Hg. The difference between the water levels in the beaker and buret was negligible. The vapor pressure of water at 25oC is 23.8 mm Hg. Based on the information provided and the lab handout, what pressure of hydrogen is collected, in atmospheres? Note: Your answer is assumed to be reduced to the highest power possible. Your Answer:__________x10 units_____ Using the data collected, calculate the moles of hydrogen collected. Your Answer:__________x10 units_____ Upon electrolysis, the metal is oxidized to a 2+ valence state. Based on this information, how many moles of metal are present? Your Answer:__________x10 units_____ Use the…
A student made measurements on some electrochemical cells and calculated three quantities: • The standard reaction free energy AG". • The equilibrium constant K at 25.0 °C. • The cell potential under standard conditions E. His results are listed below. Unfortunately, the student may have made some mistakes. Examine his results carefully and tick the box next to the incorrect quantity in each row, if any. Note: If there is a mistake in a row, only one of the three quantities listed is wrong. Also, you may assume the number of significant digits in each quantity is correct. Also note: for each cell, the number n of electrons transferred per redox reaction is 1. calculated quantities (Check the box next to any that are wrong.) cell n 46° K 1 - 124. kJ/mol 5.30 x 10 21 -1.28 V -18 4.53 x 10 B 1 - 99. kJ/mol -1.03 V -7 2.20 x 10 1 - 38. kJ/mol 0.39 V
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