Wavelength (um) 2.5 5.0 10 14 25 CH rock = C ~0.2% H2O impurity Combination band H. H stretch с —н stretch C = C C-C stretch H. CH2 гоck H C=N stretch H' C=N: C = H. C =C twist Acrylonitrile CH2 bend C CH wag CH2 wag 4000 3600 3200 2800 2400 2000 1800 1600 1400 1200 1000 800 600 400 Wavenumber (cm-1)

Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter15: Introduction To Electronic Spectroscopy And Structure
Section: Chapter Questions
Problem 15.59E: Would the light from fireflies be considered an example of a fluorescence or a phosphorescence...
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A major short-lived, neutral species in flames is OH.(a) What is unusual about the electronic structure of OH?(b) Use the standard heat of formation of OH(g) (39.0 kJ/mol)and bond energies to calculate the O-H bond energy in OH(g).(c) From the average value for the O-H bond energy in Table and your value for the O-H bond energy in OH(g) find the energy needed to break the first O-H bond in water.

Wavelength (um)
2.5
5.0
10
14
25
CH rock
= C
~0.2% H2O
impurity
Combination
band
H.
H
stretch
с —н
stretch
C = C
C-C
stretch
H.
CH2 гоck H
C=N
stretch
H'
C=N:
C =
H.
C =C twist
Acrylonitrile
CH2
bend
C
CH wag
CH2 wag
4000 3600 3200 2800 2400 2000
1800
1600
1400
1200
1000
800
600
400
Wavenumber (cm-1)
Transcribed Image Text:Wavelength (um) 2.5 5.0 10 14 25 CH rock = C ~0.2% H2O impurity Combination band H. H stretch с —н stretch C = C C-C stretch H. CH2 гоck H C=N stretch H' C=N: C = H. C =C twist Acrylonitrile CH2 bend C CH wag CH2 wag 4000 3600 3200 2800 2400 2000 1800 1600 1400 1200 1000 800 600 400 Wavenumber (cm-1)
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