Water has a vapor pressure of 31.8 mm Hg at 30°C and a heat of vaporization of 40.657 kJ/mol. Using the Clausius-Clapeyron equation given below, determine the vapor pressure of water at 93°C in mm Hg . (R=8.3145 J/mol*K; T=K) ln P2/P1 = -ΔHvap/R(1/T2− 1/T1)

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Water has a vapor pressure of 31.8 mm Hg at 30°C and a heat of vaporization of 40.657 kJ/mol. Using the Clausius-Clapeyron equation given below, determine the vapor pressure of water at 93°C in mm Hg . (R=8.3145 J/mol*K; T=K)
ln P2/P1 = -ΔHvap/R(1/T2− 1/T1)

 

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The clausius-clapeyron equation is mainly used to find out the vapor pressure at a particular temperature. if the value of HVap and the vapor pressure of a liquid is known at another temperature. The clausius-clapeyron equation is represented as:

lnP2P1=-HVapR1T2-1T1         (1)

P1 and P2 = Vapor pressures of liquid at temperatures T1 and T2 

HVap = Enthalpy of vaporization

R = Universal gas constant

 

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