Volume acetic acid: 20.0 mL Volume Isopentyl alcohol: 15.0 mL Mass of Isopentyl Acetate collected: 9.775 grams Density of acetic acid: 1.049 g/mL Density of Isopentyl alcohol: 0.813 g/mL

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
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please help find the Percent yeild and limiting regent given the collected data

Volume acetic acid: 20.0 mL
Volume Isopentyl alcohol: 15.0 mL
Mass of Isopentyl Acetate collected: 9.775 grams
Density of acetic acid: 1.049 g/mL
Density of Isopentyl alcohol: 0.813 g/mL

 

**Percent Yield of Isoamyl Acetate Based on the Limiting Reagent**

**Topic: Chemistry | Subtopic: Stoichiometry and Limiting Reagents**

---

**Objective:**
Calculate the percent yield of isoamyl acetate based on the limiting reagent.

**Introduction:**
In chemical reactions, the limiting reagent dictates how much of the product can be produced. Here, we explore a reaction to determine the percent yield of isoamyl acetate (product B) using stoichiometric calculations. 

**Reaction:**
\[ \text{Reaction: A} \rightarrow \text{B} \]

**Given Data:**
- Mass of reactant A: 5.00 g
- Molar mass of A: 136 g/mol
- Molar ratio of A to B: 1:1
- Molar mass of B: 181 g/mol

**Calculation:**

To find the theoretical yield of B:
1. Convert the mass of A to moles.
2. Use the molar ratio to convert moles of A to moles of B.
3. Convert moles of B to grams.

Mathematical setup:
\[ \text{5.00 g A} \times \left( \frac{1 \text{ mol A}}{136 \text{ g A}} \right) \times \left( \frac{1 \text{ mol B}}{1 \text{ mol A}} \right) \times \left( \frac{181 \text{ g B}}{1 \text{ mol B}} \right) = 6.65 \text{ g B} \]

This can be expressed as:

**Step-by-Step Calculation:**

1. **Convert grams of A to moles of A:**
   \[
   5.00 \text{ g A} \times \left( \frac{1 \text{ mol A}}{136 \text{ g A}} \right) = 0.03676 \text{ mol A}
   \]

2. **Convert moles of A to moles of B** based on the given 1:1 molar ratio:
   \[
   0.03676 \text{ mol A} \times \left( \frac{1 \text{ mol B}}{1 \text{ mol A}} \right) = 0.03676 \text{ mol B}
Transcribed Image Text:**Percent Yield of Isoamyl Acetate Based on the Limiting Reagent** **Topic: Chemistry | Subtopic: Stoichiometry and Limiting Reagents** --- **Objective:** Calculate the percent yield of isoamyl acetate based on the limiting reagent. **Introduction:** In chemical reactions, the limiting reagent dictates how much of the product can be produced. Here, we explore a reaction to determine the percent yield of isoamyl acetate (product B) using stoichiometric calculations. **Reaction:** \[ \text{Reaction: A} \rightarrow \text{B} \] **Given Data:** - Mass of reactant A: 5.00 g - Molar mass of A: 136 g/mol - Molar ratio of A to B: 1:1 - Molar mass of B: 181 g/mol **Calculation:** To find the theoretical yield of B: 1. Convert the mass of A to moles. 2. Use the molar ratio to convert moles of A to moles of B. 3. Convert moles of B to grams. Mathematical setup: \[ \text{5.00 g A} \times \left( \frac{1 \text{ mol A}}{136 \text{ g A}} \right) \times \left( \frac{1 \text{ mol B}}{1 \text{ mol A}} \right) \times \left( \frac{181 \text{ g B}}{1 \text{ mol B}} \right) = 6.65 \text{ g B} \] This can be expressed as: **Step-by-Step Calculation:** 1. **Convert grams of A to moles of A:** \[ 5.00 \text{ g A} \times \left( \frac{1 \text{ mol A}}{136 \text{ g A}} \right) = 0.03676 \text{ mol A} \] 2. **Convert moles of A to moles of B** based on the given 1:1 molar ratio: \[ 0.03676 \text{ mol A} \times \left( \frac{1 \text{ mol B}}{1 \text{ mol A}} \right) = 0.03676 \text{ mol B}
**Determining the Limiting Reagent:**

When conducting a chemical reaction, identifying the limiting reagent is crucial as it determines the maximum amount of product that can be formed. In this example, we will ignore sulfuric acid since it acts as a catalyst and does not affect the overall stoichiometry of the reaction.

**Example Reaction:**

For the general reaction:
\[ \text{A} + \text{B} \rightarrow \text{C} \]

**Calculating the Moles of Reactant A:**

Assume we have a reactant \( \text{A} \) with a mass of 20.00 grams. To convert this mass into moles, use the molar mass (MW) of \( \text{A} \). The number of moles of \( \text{A} \) is calculated as follows:

\[ 20.00 \text{ g A} \times \left( \frac{1 \text{ mol A}}{\text{MW A}} \right) \times 1 = \text{mole ratio A} \]

This can be represented more generally as:

\[ 20.00 \text{ g A} \times \left( \frac{1 \text{ mol A}}{\text{MW A}} \right) \times \left( \frac{1}{1 \text{ mol A}} \right) = \text{mole ratio A} \]

Here’s the breakdown:
1. **Mass of A:** \( 20.00 \) grams
2. **Conversion Factor:** \(\left( \frac{1 \text{ mol A}}{\text{MW A}} \right)\) (The reciprocal of the molar mass of \( \text{A} \)),
3. **Stoichiometric Coefficient:** \(\left( \frac{1}{1 \text{ mol A}} \right)\) (assuming a 1:1 mole ratio from the balanced equation).

By substituting the molar mass of A (MW A) into the equation, you can calculate the mole ratio of A, which will aid in determining if \( \text{A} \) is the limiting reagent in this reaction. This method can be applied similarly to reactant \( \text{B} \) to compare which reactant will limit the formation of product \( \text{C} \).
Transcribed Image Text:**Determining the Limiting Reagent:** When conducting a chemical reaction, identifying the limiting reagent is crucial as it determines the maximum amount of product that can be formed. In this example, we will ignore sulfuric acid since it acts as a catalyst and does not affect the overall stoichiometry of the reaction. **Example Reaction:** For the general reaction: \[ \text{A} + \text{B} \rightarrow \text{C} \] **Calculating the Moles of Reactant A:** Assume we have a reactant \( \text{A} \) with a mass of 20.00 grams. To convert this mass into moles, use the molar mass (MW) of \( \text{A} \). The number of moles of \( \text{A} \) is calculated as follows: \[ 20.00 \text{ g A} \times \left( \frac{1 \text{ mol A}}{\text{MW A}} \right) \times 1 = \text{mole ratio A} \] This can be represented more generally as: \[ 20.00 \text{ g A} \times \left( \frac{1 \text{ mol A}}{\text{MW A}} \right) \times \left( \frac{1}{1 \text{ mol A}} \right) = \text{mole ratio A} \] Here’s the breakdown: 1. **Mass of A:** \( 20.00 \) grams 2. **Conversion Factor:** \(\left( \frac{1 \text{ mol A}}{\text{MW A}} \right)\) (The reciprocal of the molar mass of \( \text{A} \)), 3. **Stoichiometric Coefficient:** \(\left( \frac{1}{1 \text{ mol A}} \right)\) (assuming a 1:1 mole ratio from the balanced equation). By substituting the molar mass of A (MW A) into the equation, you can calculate the mole ratio of A, which will aid in determining if \( \text{A} \) is the limiting reagent in this reaction. This method can be applied similarly to reactant \( \text{B} \) to compare which reactant will limit the formation of product \( \text{C} \).
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