***Problem 6.32 Consider the Stark effect (Problem 6.31) for the n =hydrogen. There are initially nine degenerate states, y3lm (neglecting spin, of course),3 states ofand we turn on an electric field in the z direction.(a) Construct the 9 x 9 matrix representing the perturbing Hamiltonian. Partial an-swer: (300|z|3 10) = -3/6a, (31 0jz|3 20) = -3/3a, (3 1±1|z|32+1) =-(9/2)a.(b) Find the eigenvalues and their degeneracies.

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Answered: ve turn on an electric field in the z…

ve turn on an electric field in the z direction. Construct the 9 x 9 matrix representing the perturbing Har swer: (300|z|3 10) = -3/6a, (3 1 0|z|3 2 0) = -3/3a %3D

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Question

***Problem 6.32 Consider the Stark effect (Problem 6.31) for the n =
hydrogen. There are initially nine degenerate states, y3lm (neglecting spin, of course),
3 states of
and we turn on an electric field in the z direction.
(a) Construct the 9 x 9 matrix representing the perturbing Hamiltonian. Partial an-
swer: (300|z|3 10) = -3/6a, (31 0jz|3 20) = -3/3a, (3 1±1|z|32+1) =
-(9/2)a.
(b) Find the eigenvalues and their degeneracies.

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