Vapor pressure (mm Hg) 900 800 700 600 500 400 300 200 100 0 Carbon disulfide 10 20 30 Methanol 40 Ethanol 50 60 70 Temperature (℃) Heptane 80 90 100 110 The vapor pressure of propanol is 400 mm Hg at 82.0 °C. From the plot of vapor pressures vs temperature above, estimate the temperature at which the vapor pressure of ethanol is 400 mm Hg. °C The heat of vaporization of propanol would be expected to be than the heat of vaporization of ethanol.

Chemistry
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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Vapor pressure (mm Hg)
900
800
700
600
500
400
300
200
100
0
Carbon disulfide
44
Methanol
Ethanol
10 20 30
40
60 70
Temperature (°C)
50
Heptane
80 90 100
110
The vapor pressure of propanol is 400 mm Hg at 82.0 °C. From the plot of vapor pressures vs temperature above,
estimate the temperature at which the vapor pressure of ethanol is 400 mm Hg.
°℃
The heat of vaporization of propanol would be expected to be
than the heat of vaporization of ethanol.
Transcribed Image Text:Vapor pressure (mm Hg) 900 800 700 600 500 400 300 200 100 0 Carbon disulfide 44 Methanol Ethanol 10 20 30 40 60 70 Temperature (°C) 50 Heptane 80 90 100 110 The vapor pressure of propanol is 400 mm Hg at 82.0 °C. From the plot of vapor pressures vs temperature above, estimate the temperature at which the vapor pressure of ethanol is 400 mm Hg. °℃ The heat of vaporization of propanol would be expected to be than the heat of vaporization of ethanol.
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Introduction

The pressure exerted by a vapour with its condensed phases (solid or liquid) in a closed system at a specific temperature is referred to as vapour pressure, also known as vapour equilibrium pressure. It is well known that the equilibrium vapour pressure can be used to estimate how quickly a liquid will evaporate. It is recognised that there is a relationship between the tendency of particles to escape from a liquid (or a solid). A substance is typically said to as volatile if it has a high vapour pressure at room temperature. It should be mentioned that vapour pressure refers to the pressure that a vapour exhibits above a liquid surface.

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