STANDARD REDUCTION POTENTIALS INAQUEOUS SOLUTION AT 25°cStandard ReductionHalf-Reaction, Acidic SolutionPotential, E (volts)Li"(aq) + eLi(s)-3.045K*(aq) + e K(s)Rb (aq) +e- Rb(s)-2.925-2.925Ba"(aq) + 2 e- Ba(s)Sr*(aq) + 2 e - Sr(s)Ca" (aq) + 2 e Ca(s)Na (aq) + e Na(s)Mg"(aq) + 2e Mg(s)H,(g) + 2e2 H (aq)-2.90-2.89-2.87-2.714-2.37-2.25Al* (aq) + 3e Al(s)Zr**(aq) + 4 e-Zr(s)ZnS(s) + 2 e-Zn(s) + s (aq)CdS(s) + 2eCd(s) + S (aq)V**(aq) + 2 e - V(s)Mn*(aq) + 2 e Mn(s)-1.66-1.53-1.44-1.21-1.18-1.18FeS(s) + 2 e Fe(s) + S (aq)Cr"(aq) + 2 e-Cr(s)Zn"(aq) + 2 e- Zn(s)Cr"(aq) + 3 e Cr(s)HgS(s) + 2 H*(aq) + 2 e- Hg(€) + H,S(g)Ga"(aq) + 3 e- Ga(s)2 CO.(g) + 2 H*(aq) + 2 e- (COOH)(aq)-1.01-0.91-0.763-0.74-0.72-0.53-0.49Fe"(aq) + 2 e Fe(s)-0.44CP"(aq) + e Cr"(aq)Cd" (aq) + 2 e Cd(s)Se(s) + 2 H'(aq) + 2e H,Se(aq)PhSO.(s) + 2 e- Pb(s) + SO, (aq)-0.41-0.403-0.40-0.356-0.34TI*(aq) + e-Tl(s)Co"(aq) + 2 e Co(s)Ni"(aq) + 2 e- Ni(s)-0.28-0.25[SNFJ (aq) + 4e Sn(s) + 6F (aq)-0.25Agl(s) + e- Ag(s) +I(aq)Sn*(aq) + 2 e- Sn(s)-0.15-0.14Pb*(aq) + 2 e- Ph(s)N,O(g) + 6 H*(ag) + H,O() + 4e2 NH,OH (ag)2 H*(aq) + 2 e H:(g)AgBr(s) + e Ag(s) + Br (aq)-0.126-0.050.0000.10(Contines51Standard ReductionHalf-Reaction, Acidic SolutionPotential, E (volts)S(s) + 2 H*(aq) + 2 e" H,S(aq)Sn" (aq) + 2 e"- Sn"(aq)Cu"(aq) + e- Cu"(aq)SO, (aq) + 4 H*(aq) + 2 e-H,SO(aq) + H,O(e)so, (aq) + 4 H* (aq) + 2 e SO(g) + 2 H,O(e)AgCI(s) + e Ag(s) + Cl (aq)Hg.Cl,(s) + 2 e 2 Hg() + 2 CI-(aq)Cu"(aq) + 2 e" Cu(s)[RhClj (aq) + 3 e-Rh(s) + 6 CI (aq)Cu (aq) +e Cu(s)TeO,(s) + 4 H* (aq) + 4e Te(s) + 2 H,O(e)I(s) + 2 e21-(aq)HAsOa(aq) + 2 H*(aq) + 2 e- H,AsO(aq) + H:O()[P:CLJ (aq) + 2 e- [P:CL (aq) + 2 Cl (aq)O.(g) + 2 H*(aq) + 2 eH,O,(aq)[P:CLJ (aq) + 2 e Pr(s) + 4CI (aq)SBCI, (aq) + 2 e- SbCI, (aq) + 2 CI (aq)Fe"(aq) + e- Fe"(aq)Hg,"(aq) + 2 e" 2 Hg(€)Ag (aq) + e- Ag(s)Hg "(aq) + 2 e Hg(e)2 Hg*(aq) + 2 e- Hg."(aq)0.140.150.153Cu" (aq)0.170.200.2220.270.3370.440.5210.5290.5350.580.680.6820.730.750.7710.7890.79940.85520.9200.94NO, (aq) + 3 H*(aq) + 2 e- HNO,(aq) + H,O(€)NO, (aq) + 4 H*(aq) + 3 e NO(g) + 2 H,O(E)Pd*(aq) + 2 e- Pd(s)AuCl, (aq) + 3 e- Au(s) + 4 CI (aq)Br,(E) + 2 e 2 Br (aq)CIO, (aq) + 2 H*(aq) + 2 eCIO, (aq) + H,O()10, (aq) + 6 H'(aq) + 5eH,(aq) + 3 H,O()Pr"(aq) + 2 e- Pt(s)O.(g) + 4 H*(aq) + 4 e2 H,O()MnO,(s) + 4 H*(aq) + 2 e- Mn²* (aq) + 2 H,O()N,H, (aq) + 3 H*(aq) + 2 e2 NH,"(aq)Cr.0 (aq) + 14 H'(aq) + 6 e-2 Cr"(aq) + 7 H;O()Cl,g) + 2e2 a (aq)0.960.9871.001.081.191.1951.21.2291.231.241.331.3601.44BrO, (aq) + 6 H*(aq) + 6 e- Br (aq) + 3 H,O(e)CIO, (aq) + 6 H (aq) + 5e CI(aq) + 3 H;O()Au**(aq) + 3 e- Au(s)MnO, (aq) + 8 H (aq) + 5 e Mn"(aq) + 4 H,O(e)NaBiOs(s) + 6 H (aq) + 2e- Bi'*(aq) + Na*(aq) + 3 H;O()Ce" (aq) + e Ce"(aq)2 HOCI(aq) + 2 H*(aq) + 2 eCI,(g) + 2 H,O()Au'(aq) + e Au(s)PbO,(s) + So, (aq) + 4 H*(aq) + 2 e- PhSO4s) + 2 H,O(0)NiO,(s) + 4 H*(aq) + 2 eNi*(aq) + 2 H,O(€)1.471.501.5071.61.6121.631.681.6851.7512Appendix IStandard ReductionHalf-Reaction, Acidic SolutionPotential, E (volts)H,O.(aq) + 2 H"(aq) + 2e2 H,O()Pb**(aq) + 2 e - Pb**(aq)Co"(aq) + e Co (aq)F:(g) + 2e2F (aq)1.771.81.822.87 Using values from the table of standard reduction potentials, calculate the cell potential (in V) of thefollowing cells.2+2+(a) Ni(s) | Ni* (ag) || Pd** (ag) | Pd(s)V2+2+(b) Cd(s) | Cd (ag) || Ni^™ (ag) | Ni(s)IV2+(c) Fe(s), FeS(s) | S´ (ag) || Sn^" (ag) | Sn(s)

We have tp Calculate the standards potential value for the following cell reaction…

Using values from the table of standard reduction potentials, calculate the cell potential (in V) of the following cells. 2+ 2+ (a) Ni(s) | Ni* (ag) || Pd** (ag) | Pd(s) V 2+ 2+ (b) Cd(s) | Cd (ag) || Ni^™ (ag) | Ni(s) IV 2+ (c) Fe(s), FeS(s) | S´ (ag) || Sn^" (ag) | Sn(s)

Using values from the table of standard reduction potentials, calculate the cell potential (in V) of the following cells. 2+ 2+ (a) Ni(s) | Ni* (ag) || Pd** (ag) | Pd(s) V 2+ 2+ (b) Cd(s) | Cd (ag) || Ni^™ (ag) | Ni(s) IV 2+ (c) Fe(s), FeS(s) | S´ (ag) || Sn^" (ag) | Sn(s)

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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