Using values from the table of standard reduction potentials, calculate the cell potential (in V) of the following cells. 2+ 2+ (a) Ni(s) | Ni* (ag) || Pd** (ag) | Pd(s) V 2+ 2+ (b) Cd(s) | Cd (ag) || Ni^™ (ag) | Ni(s) IV 2+ (c) Fe(s), FeS(s) | S´ (ag) || Sn^" (ag) | Sn(s)
Using values from the table of standard reduction potentials, calculate the cell potential (in V) of the following cells. 2+ 2+ (a) Ni(s) | Ni* (ag) || Pd** (ag) | Pd(s) V 2+ 2+ (b) Cd(s) | Cd (ag) || Ni^™ (ag) | Ni(s) IV 2+ (c) Fe(s), FeS(s) | S´ (ag) || Sn^" (ag) | Sn(s)
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Question
![STANDARD REDUCTION POTENTIALS IN
AQUEOUS SOLUTION AT 25°c
Standard Reduction
Half-Reaction, Acidic Solution
Potential, E (volts)
Li"(aq) + eLi(s)
-3.045
K*(aq) + e K(s)
Rb (aq) +e- Rb(s)
-2.925
-2.925
Ba"(aq) + 2 e- Ba(s)
Sr*(aq) + 2 e - Sr(s)
Ca" (aq) + 2 e Ca(s)
Na (aq) + e Na(s)
Mg"(aq) + 2e Mg(s)
H,(g) + 2e2 H (aq)
-2.90
-2.89
-2.87
-2.714
-2.37
-2.25
Al* (aq) + 3e Al(s)
Zr**(aq) + 4 e-Zr(s)
ZnS(s) + 2 e-Zn(s) + s (aq)
CdS(s) + 2eCd(s) + S (aq)
V**(aq) + 2 e - V(s)
Mn*(aq) + 2 e Mn(s)
-1.66
-1.53
-1.44
-1.21
-1.18
-1.18
FeS(s) + 2 e Fe(s) + S (aq)
Cr"(aq) + 2 e-Cr(s)
Zn"(aq) + 2 e- Zn(s)
Cr"(aq) + 3 e Cr(s)
HgS(s) + 2 H*(aq) + 2 e- Hg(€) + H,S(g)
Ga"(aq) + 3 e- Ga(s)
2 CO.(g) + 2 H*(aq) + 2 e- (COOH)(aq)
-1.01
-0.91
-0.763
-0.74
-0.72
-0.53
-0.49
Fe"(aq) + 2 e Fe(s)
-0.44
CP"(aq) + e Cr"(aq)
Cd" (aq) + 2 e Cd(s)
Se(s) + 2 H'(aq) + 2e H,Se(aq)
PhSO.(s) + 2 e- Pb(s) + SO, (aq)
-0.41
-0.403
-0.40
-0.356
-0.34
TI*(aq) + e-Tl(s)
Co"(aq) + 2 e Co(s)
Ni"(aq) + 2 e- Ni(s)
-0.28
-0.25
[SNFJ (aq) + 4e Sn(s) + 6F (aq)
-0.25
Agl(s) + e- Ag(s) +I(aq)
Sn*(aq) + 2 e- Sn(s)
-0.15
-0.14
Pb*(aq) + 2 e- Ph(s)
N,O(g) + 6 H*(ag) + H,O() + 4e2 NH,OH (ag)
2 H*(aq) + 2 e H:(g)
AgBr(s) + e Ag(s) + Br (aq)
-0.126
-0.05
0.000
0.10
(Contines
51
Standard Reduction
Half-Reaction, Acidic Solution
Potential, E (volts)
S(s) + 2 H*(aq) + 2 e" H,S(aq)
Sn" (aq) + 2 e"- Sn"(aq)
Cu"(aq) + e- Cu"(aq)
SO, (aq) + 4 H*(aq) + 2 e-H,SO(aq) + H,O(e)
so, (aq) + 4 H* (aq) + 2 e SO(g) + 2 H,O(e)
AgCI(s) + e Ag(s) + Cl (aq)
Hg.Cl,(s) + 2 e 2 Hg() + 2 CI-(aq)
Cu"(aq) + 2 e" Cu(s)
[RhClj (aq) + 3 e-Rh(s) + 6 CI (aq)
Cu (aq) +e Cu(s)
TeO,(s) + 4 H* (aq) + 4e Te(s) + 2 H,O(e)
I(s) + 2 e21-(aq)
HAsOa(aq) + 2 H*(aq) + 2 e- H,AsO(aq) + H:O()
[P:CLJ (aq) + 2 e- [P:CL (aq) + 2 Cl (aq)
O.(g) + 2 H*(aq) + 2 eH,O,(aq)
[P:CLJ (aq) + 2 e Pr(s) + 4CI (aq)
SBCI, (aq) + 2 e- SbCI, (aq) + 2 CI (aq)
Fe"(aq) + e- Fe"(aq)
Hg,"(aq) + 2 e" 2 Hg(€)
Ag (aq) + e- Ag(s)
Hg "(aq) + 2 e Hg(e)
2 Hg*(aq) + 2 e- Hg."(aq)
0.14
0.15
0.153
Cu" (aq)
0.17
0.20
0.222
0.27
0.337
0.44
0.521
0.529
0.535
0.58
0.68
0.682
0.73
0.75
0.771
0.789
0.7994
0.855
2
0.920
0.94
NO, (aq) + 3 H*(aq) + 2 e- HNO,(aq) + H,O(€)
NO, (aq) + 4 H*(aq) + 3 e NO(g) + 2 H,O(E)
Pd*(aq) + 2 e- Pd(s)
AuCl, (aq) + 3 e- Au(s) + 4 CI (aq)
Br,(E) + 2 e 2 Br (aq)
CIO, (aq) + 2 H*(aq) + 2 eCIO, (aq) + H,O()
10, (aq) + 6 H'(aq) + 5eH,(aq) + 3 H,O()
Pr"(aq) + 2 e- Pt(s)
O.(g) + 4 H*(aq) + 4 e2 H,O()
MnO,(s) + 4 H*(aq) + 2 e- Mn²* (aq) + 2 H,O()
N,H, (aq) + 3 H*(aq) + 2 e2 NH,"(aq)
Cr.0 (aq) + 14 H'(aq) + 6 e-2 Cr"(aq) + 7 H;O()
Cl,g) + 2e2 a (aq)
0.96
0.987
1.00
1.08
1.19
1.195
1.2
1.229
1.23
1.24
1.33
1.360
1.44
BrO, (aq) + 6 H*(aq) + 6 e- Br (aq) + 3 H,O(e)
CIO, (aq) + 6 H (aq) + 5e CI(aq) + 3 H;O()
Au**(aq) + 3 e- Au(s)
MnO, (aq) + 8 H (aq) + 5 e Mn"(aq) + 4 H,O(e)
NaBiOs(s) + 6 H (aq) + 2e- Bi'*(aq) + Na*(aq) + 3 H;O()
Ce" (aq) + e Ce"(aq)
2 HOCI(aq) + 2 H*(aq) + 2 eCI,(g) + 2 H,O()
Au'(aq) + e Au(s)
PbO,(s) + So, (aq) + 4 H*(aq) + 2 e- PhSO4s) + 2 H,O(0)
NiO,(s) + 4 H*(aq) + 2 eNi*(aq) + 2 H,O(€)
1.47
1.50
1.507
1.6
1.61
2
1.63
1.68
1.685
1.7
512
Appendix I
Standard Reduction
Half-Reaction, Acidic Solution
Potential, E (volts)
H,O.(aq) + 2 H"(aq) + 2e2 H,O()
Pb**(aq) + 2 e - Pb**(aq)
Co"(aq) + e Co (aq)
F:(g) + 2e2F (aq)
1.77
1.8
1.82
2.87](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fd90db30f-81f7-4e6a-8ae7-b9c16219a773%2F455db793-4c62-4f0b-af8f-1f50878fdb25%2Fl1tfeht_processed.png&w=3840&q=75)
Transcribed Image Text:STANDARD REDUCTION POTENTIALS IN
AQUEOUS SOLUTION AT 25°c
Standard Reduction
Half-Reaction, Acidic Solution
Potential, E (volts)
Li"(aq) + eLi(s)
-3.045
K*(aq) + e K(s)
Rb (aq) +e- Rb(s)
-2.925
-2.925
Ba"(aq) + 2 e- Ba(s)
Sr*(aq) + 2 e - Sr(s)
Ca" (aq) + 2 e Ca(s)
Na (aq) + e Na(s)
Mg"(aq) + 2e Mg(s)
H,(g) + 2e2 H (aq)
-2.90
-2.89
-2.87
-2.714
-2.37
-2.25
Al* (aq) + 3e Al(s)
Zr**(aq) + 4 e-Zr(s)
ZnS(s) + 2 e-Zn(s) + s (aq)
CdS(s) + 2eCd(s) + S (aq)
V**(aq) + 2 e - V(s)
Mn*(aq) + 2 e Mn(s)
-1.66
-1.53
-1.44
-1.21
-1.18
-1.18
FeS(s) + 2 e Fe(s) + S (aq)
Cr"(aq) + 2 e-Cr(s)
Zn"(aq) + 2 e- Zn(s)
Cr"(aq) + 3 e Cr(s)
HgS(s) + 2 H*(aq) + 2 e- Hg(€) + H,S(g)
Ga"(aq) + 3 e- Ga(s)
2 CO.(g) + 2 H*(aq) + 2 e- (COOH)(aq)
-1.01
-0.91
-0.763
-0.74
-0.72
-0.53
-0.49
Fe"(aq) + 2 e Fe(s)
-0.44
CP"(aq) + e Cr"(aq)
Cd" (aq) + 2 e Cd(s)
Se(s) + 2 H'(aq) + 2e H,Se(aq)
PhSO.(s) + 2 e- Pb(s) + SO, (aq)
-0.41
-0.403
-0.40
-0.356
-0.34
TI*(aq) + e-Tl(s)
Co"(aq) + 2 e Co(s)
Ni"(aq) + 2 e- Ni(s)
-0.28
-0.25
[SNFJ (aq) + 4e Sn(s) + 6F (aq)
-0.25
Agl(s) + e- Ag(s) +I(aq)
Sn*(aq) + 2 e- Sn(s)
-0.15
-0.14
Pb*(aq) + 2 e- Ph(s)
N,O(g) + 6 H*(ag) + H,O() + 4e2 NH,OH (ag)
2 H*(aq) + 2 e H:(g)
AgBr(s) + e Ag(s) + Br (aq)
-0.126
-0.05
0.000
0.10
(Contines
51
Standard Reduction
Half-Reaction, Acidic Solution
Potential, E (volts)
S(s) + 2 H*(aq) + 2 e" H,S(aq)
Sn" (aq) + 2 e"- Sn"(aq)
Cu"(aq) + e- Cu"(aq)
SO, (aq) + 4 H*(aq) + 2 e-H,SO(aq) + H,O(e)
so, (aq) + 4 H* (aq) + 2 e SO(g) + 2 H,O(e)
AgCI(s) + e Ag(s) + Cl (aq)
Hg.Cl,(s) + 2 e 2 Hg() + 2 CI-(aq)
Cu"(aq) + 2 e" Cu(s)
[RhClj (aq) + 3 e-Rh(s) + 6 CI (aq)
Cu (aq) +e Cu(s)
TeO,(s) + 4 H* (aq) + 4e Te(s) + 2 H,O(e)
I(s) + 2 e21-(aq)
HAsOa(aq) + 2 H*(aq) + 2 e- H,AsO(aq) + H:O()
[P:CLJ (aq) + 2 e- [P:CL (aq) + 2 Cl (aq)
O.(g) + 2 H*(aq) + 2 eH,O,(aq)
[P:CLJ (aq) + 2 e Pr(s) + 4CI (aq)
SBCI, (aq) + 2 e- SbCI, (aq) + 2 CI (aq)
Fe"(aq) + e- Fe"(aq)
Hg,"(aq) + 2 e" 2 Hg(€)
Ag (aq) + e- Ag(s)
Hg "(aq) + 2 e Hg(e)
2 Hg*(aq) + 2 e- Hg."(aq)
0.14
0.15
0.153
Cu" (aq)
0.17
0.20
0.222
0.27
0.337
0.44
0.521
0.529
0.535
0.58
0.68
0.682
0.73
0.75
0.771
0.789
0.7994
0.855
2
0.920
0.94
NO, (aq) + 3 H*(aq) + 2 e- HNO,(aq) + H,O(€)
NO, (aq) + 4 H*(aq) + 3 e NO(g) + 2 H,O(E)
Pd*(aq) + 2 e- Pd(s)
AuCl, (aq) + 3 e- Au(s) + 4 CI (aq)
Br,(E) + 2 e 2 Br (aq)
CIO, (aq) + 2 H*(aq) + 2 eCIO, (aq) + H,O()
10, (aq) + 6 H'(aq) + 5eH,(aq) + 3 H,O()
Pr"(aq) + 2 e- Pt(s)
O.(g) + 4 H*(aq) + 4 e2 H,O()
MnO,(s) + 4 H*(aq) + 2 e- Mn²* (aq) + 2 H,O()
N,H, (aq) + 3 H*(aq) + 2 e2 NH,"(aq)
Cr.0 (aq) + 14 H'(aq) + 6 e-2 Cr"(aq) + 7 H;O()
Cl,g) + 2e2 a (aq)
0.96
0.987
1.00
1.08
1.19
1.195
1.2
1.229
1.23
1.24
1.33
1.360
1.44
BrO, (aq) + 6 H*(aq) + 6 e- Br (aq) + 3 H,O(e)
CIO, (aq) + 6 H (aq) + 5e CI(aq) + 3 H;O()
Au**(aq) + 3 e- Au(s)
MnO, (aq) + 8 H (aq) + 5 e Mn"(aq) + 4 H,O(e)
NaBiOs(s) + 6 H (aq) + 2e- Bi'*(aq) + Na*(aq) + 3 H;O()
Ce" (aq) + e Ce"(aq)
2 HOCI(aq) + 2 H*(aq) + 2 eCI,(g) + 2 H,O()
Au'(aq) + e Au(s)
PbO,(s) + So, (aq) + 4 H*(aq) + 2 e- PhSO4s) + 2 H,O(0)
NiO,(s) + 4 H*(aq) + 2 eNi*(aq) + 2 H,O(€)
1.47
1.50
1.507
1.6
1.61
2
1.63
1.68
1.685
1.7
512
Appendix I
Standard Reduction
Half-Reaction, Acidic Solution
Potential, E (volts)
H,O.(aq) + 2 H"(aq) + 2e2 H,O()
Pb**(aq) + 2 e - Pb**(aq)
Co"(aq) + e Co (aq)
F:(g) + 2e2F (aq)
1.77
1.8
1.82
2.87
![Using values from the table of standard reduction potentials, calculate the cell potential (in V) of the
following cells.
2+
2+
(a) Ni(s) | Ni* (ag) || Pd** (ag) | Pd(s)
V
2+
2+
(b) Cd(s) | Cd (ag) || Ni^™ (ag) | Ni(s)
IV
2+
(c) Fe(s), FeS(s) | S´ (ag) || Sn^" (ag) | Sn(s)](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fd90db30f-81f7-4e6a-8ae7-b9c16219a773%2F455db793-4c62-4f0b-af8f-1f50878fdb25%2Fx02mhcq_processed.png&w=3840&q=75)
Transcribed Image Text:Using values from the table of standard reduction potentials, calculate the cell potential (in V) of the
following cells.
2+
2+
(a) Ni(s) | Ni* (ag) || Pd** (ag) | Pd(s)
V
2+
2+
(b) Cd(s) | Cd (ag) || Ni^™ (ag) | Ni(s)
IV
2+
(c) Fe(s), FeS(s) | S´ (ag) || Sn^" (ag) | Sn(s)
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