Using the half reaction data in (Table 9.3; write balanced overall reactions for the following redox processes. Calculate the Eº, pe° and AG values for each overall reaction. Indicate whether each reaction is thermodynamically favorable under standard conditions.
Using the half reaction data in (Table 9.3; write balanced overall reactions for the following redox processes. Calculate the Eº, pe° and AG values for each overall reaction. Indicate whether each reaction is thermodynamically favorable under standard conditions.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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
Transcribed Image Text:Using the half reaction data in (Table 9.3), write balanced overall reactions for the following redox processes. Calculate the E⁰, pe⁰ and ΔG⁰ values for each overall reaction. Indicate whether each reaction is thermodynamically favorable under standard conditions.
i) Oxidation of Mn²⁺ to MnO₂(s) using I₂(aq) to form I⁻.
ii) Oxidation of Pb(s) to Pb²⁺ by Zn²⁺ to form Zn(s).

Transcribed Image Text:Below is a transcription and explanation of the chemical equilibrium data from the provided image. This content is suitable for an educational setting, focusing on chemistry.
### Chemical Equilibrium Constants
The table presents a series of chemical reactions, along with their respective equilibrium constants (Log K), standard electrode potentials (pe°), and reduction potentials (E° in mV). These values are critical in understanding the behavior of reactions in various conditions and can be used to predict reaction spontaneity and direction.
#### Key
- **Reaction**: Represents the chemical equation for the transformation being studied.
- **Log K**: The logarithm of the equilibrium constant, providing insights into the favorability of a reaction at standard conditions.
- **pe°**: The standard electron potential, indicating the tendency of a substance to gain or lose electrons.
- **E° (mV)**: The standard reduction potential in millivolts, which also provides similar information to pe°.
#### Sample Reactions and Their Values
1. **NO₃⁻ + 2e⁻ + 2H⁺ ↔ NO₂⁻ + H₂O**
- Log K: 28.57
- pe°: 3.63
- E° (mV): 421
2. **NO₃⁻ + 10e⁻ + 10H⁺ ↔ NH₄⁺ + 3H₂O**
- Log K: 110.98
- pe°: 8.06
- E° (mV): 1348
3. **Cr₂O₇²⁻ + 6e⁻ + 14H⁺ ↔ 2Cr³⁺ + 7H₂O**
- Log K: 130.94
- pe°: 8.18
- E° (mV): 1392
4. **Fe³⁺ + e⁻ ↔ Fe²⁺**
- Log K: 15.04
- pe°: 1.31
- E° (mV): 771
5. **O₂(g) + 4e⁻ + 4H⁺ ↔ 2H₂O**
- Log K: 83.01
- pe°: 5.80
- E° (m
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