Write a balanced half-reaction for the oxidation of solid manganese dioxide (MnO₂) to permanganate ion (MnO4) in acidic aqueous solution. Be sure to add physical state symbols where appropriate.
Write a balanced half-reaction for the oxidation of solid manganese dioxide (MnO₂) to permanganate ion (MnO4) in acidic aqueous solution. Be sure to add physical state symbols where appropriate.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:**Understanding Half-Reactions: Manganese Dioxide Oxidation**
**Objective:**
Learn to write a balanced half-reaction for the oxidation of solid manganese dioxide (MnO₂) to permanganate ion (MnO₄⁻) in acidic aqueous solution, including physical state symbols.
**Step-by-Step Guide:**
1. **Identify Reactants and Products:**
- Reactant: Solid manganese dioxide (MnO₂, s)
- Product: Permanganate ion (MnO₄⁻, aq)
2. **Understanding the Reaction Conditions:**
- The reaction occurs in an acidic aqueous solution, indicating the presence of protons (H⁺, aq).
3. **Balancing the Half-Reaction:**
- **Mass Balance:** Ensure the number of Mn atoms and O atoms is the same on both sides.
- **Charge Balance:** Adjust for charge with electrons (e⁻).
4. **Incorporate Physical State Symbols:**
- Indicate MnO₂ as solid (s) and MnO₄⁻ as aqueous (aq).
**Outcome:**
The balanced half-reaction combines mass and charge conservation, factoring in additional H₂O and H⁺ molecules needed to balance O and H atoms.
**Conclusion:**
Writing balanced half-reactions requires attention to detail in stoichiometry and electron transfer, fundamental in understanding redox processes in chemistry.
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