Using the (C3v) group character table below, determine the symmetry representation of the six vibrations of (NH3) The internal coordinate of NH3 can be set as in the below figure. Using projection operators, find the symmetry adapted vibrational coordinates of the six vibrations.
Using the (C3v) group character table below, determine the symmetry representation of the six vibrations of (NH3) The internal coordinate of NH3 can be set as in the below figure. Using projection operators, find the symmetry adapted vibrational coordinates of the six vibrations.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:10. Using the (C3) group character table below, determine the symmetry
representation of the six vibrations of (NH3) The internal coordinate of
NH3 can be set as in the below figure. Using projection operators, find
the symmetry adapted vibrational coordinates of the six vibrations.
A₁
A₂
E
E
1
1
2
2C3
1
-1
30v
1
-1
0
h = 6
Z
Rz
(x,y) (Rx, Ry)
AT₂
40
Arz
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