Using bond enthalpies, estimate the standard heat of the reaction for the hydrobromination of ethylene: Br H CH,=CH, + HBr - ČH;-CH2 TABLE 4-5. EMPIRICAL BOND ENTHALPIES AT 25°C (kcal/mole) Bond AH Bond H-H 104 C-CI 79 H-F H-CI C-Br C-S 135 66 103 62 C=8 C-N C=N C=N N-N H-Br 88 114 0-0 33 70 0=0 118 147 111 99 84 170 210 38 100 226 0-H C-H C-0 N=N C=0 N=N N-H C-C C=C C=C 83 147 93 F-F Cl-CI Br-Br 37 194 58 C--F 105 46 C(s, graphite) - C(g) 172

Chemistry: The Molecular Science
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Chapter4: Energy And Chemical Reactions
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Using bond enthalpies, estimate the standard heat of the reaction for the
hydrobromination of ethylene:
Br H
CH,=CH, + HBr
ČH;-CH2
TABLE 4-5. EMPIRICAL BOND ENTHALPIES
AT 25°C
(kcal/mole)
Bond
AH
Bond
ΔΗ
H-H
104
C-CI
79
H-F
135
C-Br
66
H-CI
H-Br
103
88
33
C-S
62
C=S
114
0-0
C-N
70
0=0
118
C=N
147
C=N
N-N
0-H
111
210
C-H
99
38
C-0
84
N=N
100
C=0
170
N=N
226
C-C
C=C
C=C
C--F
N-H
F-F
Cl-CI
93
37
58
83
147
194
105
Br-Br
46
C(s, graphite)
C(g) 172
%3D
Transcribed Image Text:Using bond enthalpies, estimate the standard heat of the reaction for the hydrobromination of ethylene: Br H CH,=CH, + HBr ČH;-CH2 TABLE 4-5. EMPIRICAL BOND ENTHALPIES AT 25°C (kcal/mole) Bond AH Bond ΔΗ H-H 104 C-CI 79 H-F 135 C-Br 66 H-CI H-Br 103 88 33 C-S 62 C=S 114 0-0 C-N 70 0=0 118 C=N 147 C=N N-N 0-H 111 210 C-H 99 38 C-0 84 N=N 100 C=0 170 N=N 226 C-C C=C C=C C--F N-H F-F Cl-CI 93 37 58 83 147 194 105 Br-Br 46 C(s, graphite) C(g) 172 %3D
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