Use the van der Waals equation to calculate the pressure, in atm, of 37.49 mol of hydrogen at 108 °C in a 1.65L container. Values of van der Waals Constants for Some Common Gases atm L2 a mol? bl mol Gas Не 0.034 0.0237 H2 N2 O2 Cl2 CO2 CH4 0.244 0.0266 0.0391 0.0318 1.39 1.36 6.49 0.0562 3.59 0.0427 2.25 0.0428 Answer:
Use the van der Waals equation to calculate the pressure, in atm, of 37.49 mol of hydrogen at 108 °C in a 1.65L container. Values of van der Waals Constants for Some Common Gases atm L2 a mol? bl mol Gas Не 0.034 0.0237 H2 N2 O2 Cl2 CO2 CH4 0.244 0.0266 0.0391 0.0318 1.39 1.36 6.49 0.0562 3.59 0.0427 2.25 0.0428 Answer:
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
Related questions
Question
![### Van der Waals Equation Application
**Problem Statement:**
Use the van der Waals equation to calculate the pressure, in atm, of 37.49 mol of hydrogen at 108 °C in a 1.65 L container.
**Van der Waals Constants for Some Common Gases:**
| Gas | \( a \, \left(\frac{\text{atm} \cdot \text{L}^2}{\text{mol}^2}\right) \) | \( b \, \left(\frac{\text{L}}{\text{mol}}\right) \) |
|------|------------------------------------------------|----------------------------------------------|
| He | 0.034 | 0.0237 |
| H₂ | 0.244 | 0.0266 |
| N₂ | 1.39 | 0.0391 |
| O₂ | 1.36 | 0.0318 |
| Cl₂ | 6.49 | 0.0562 |
| CO₂ | 3.59 | 0.0427 |
| CH₄ | 2.25 | 0.0428 |
**Calculation:**
1. Convert temperature from Celsius to Kelvin:
\[
T(K) = 108 + 273.15 = 381.15 \, K
\]
2. Use the van der Waals equation to find the pressure \( P \):
\[
\left( P + \frac{an^2}{V^2} \right) \times (V - nb) = nRT
\]
where,
- \( n = 37.49 \, \text{mol} \)
- \( V = 1.65 \, \text{L} \)
- \( R = 0.0821 \, \frac{\text{L atm}}{\text{mol K}} \)
- \( a = 0.244 \, \frac{\text{atm} \cdot \text{L}^2}{\text{mol}^2} \)
- \( b = 0.0266 \, \frac{\text{L}}{\text{mol}} \)
- \( T = 381.15 \, K \](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fe3925343-d6c3-4a25-992b-202f02b2b634%2F697a9544-70a5-43bc-8b00-1399eec76216%2Fd7zezw_processed.jpeg&w=3840&q=75)
Transcribed Image Text:### Van der Waals Equation Application
**Problem Statement:**
Use the van der Waals equation to calculate the pressure, in atm, of 37.49 mol of hydrogen at 108 °C in a 1.65 L container.
**Van der Waals Constants for Some Common Gases:**
| Gas | \( a \, \left(\frac{\text{atm} \cdot \text{L}^2}{\text{mol}^2}\right) \) | \( b \, \left(\frac{\text{L}}{\text{mol}}\right) \) |
|------|------------------------------------------------|----------------------------------------------|
| He | 0.034 | 0.0237 |
| H₂ | 0.244 | 0.0266 |
| N₂ | 1.39 | 0.0391 |
| O₂ | 1.36 | 0.0318 |
| Cl₂ | 6.49 | 0.0562 |
| CO₂ | 3.59 | 0.0427 |
| CH₄ | 2.25 | 0.0428 |
**Calculation:**
1. Convert temperature from Celsius to Kelvin:
\[
T(K) = 108 + 273.15 = 381.15 \, K
\]
2. Use the van der Waals equation to find the pressure \( P \):
\[
\left( P + \frac{an^2}{V^2} \right) \times (V - nb) = nRT
\]
where,
- \( n = 37.49 \, \text{mol} \)
- \( V = 1.65 \, \text{L} \)
- \( R = 0.0821 \, \frac{\text{L atm}}{\text{mol K}} \)
- \( a = 0.244 \, \frac{\text{atm} \cdot \text{L}^2}{\text{mol}^2} \)
- \( b = 0.0266 \, \frac{\text{L}}{\text{mol}} \)
- \( T = 381.15 \, K \
Expert Solution

This question has been solved!
Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.
This is a popular solution!
Trending now
This is a popular solution!
Step by step
Solved in 2 steps with 1 images

Recommended textbooks for you

Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning

Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education

Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning

Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning

Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education

Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning

Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education

Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning

Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY