Use the References to access important values if needed for thisquestion.The normal boiling point of ether (C2H5OC2H5) is 34.5°C. If 46.58 grams of the nonvolatile nonelectrolytealizarin (C14H804), are dissolved in 233.9 grams of ether,what is the boiling point of the resulting solution? Kpp forether is 2.02 °C/m.°CSubmit Answer2 question attempts remaining

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Chemistry: An Atoms First Approach

2nd Edition

ISBN:9781305079243

Author:Steven S. Zumdahl, Susan A. Zumdahl

Publisher:Steven S. Zumdahl, Susan A. Zumdahl

Chapter10: Properties Of Solutions

Section: Chapter Questions

Problem 101AE

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An aqueous solution containing 10.0 g of starch per liter has an osmotic pressure of 3.8 mm Hg at 25 C. (a) What is the average molar mass of starch? (The result is an average because not all starch molecules are identical.) (b) What is the freezing point of the solution? Would it be easy to determine the molecular weight of starch by measuring the freezing point depression? (Assume that the molarity and molality are the same for this solution.)
Butylated hydroxyanisole (BHA) is used in margarine and other fats and oils. (It is used as an antioxidant and prolongs the shelf life of the food.) What is the molar mass of BHA if 0.640 g of the compound, dissolved in 25.0 g of chloroform, produces a solution whose boiling point is 62.22 C?
Sodium chloride (NaCl) is commonly used to melt ice on roads during the winter. Calcium chloride (CaCl2) is sometimes used for this purpose too. Let us compare the effectiveness of equal masses of these two compounds in lowering the freezing point of water, by calculating the freezing point depression of solutions containing 200. g of each salt in 1.00 kg of water. (An advantage of CaCl2 is that it acts more quickly because it is hygroscopic, that is. it absorbs moisture from the air to give a solution and begin the process. A disadvantage is that this compound is more costly.)
Calculate the freezing point and normal boiling points of each of the following aqueous solutions. (a) 2.63 m acetic acid (b) 33.0 % by mass lactose, C12H22O11 (c) 32.15 mL of ethylene glycol, C2H6O2(d=1.113g/mL) in 624 mL of water (d=1.00g/mL)
You have two aqueous solutions separated by a semipermeable membrane. One contains 5.85 g of NaCl dissolved in 100. mL of solution, and the other contains 8.88 g of KNO3 dissolved in 100. mL of solution. In which direction will solvent flow: from the NaCl solution to the KNO3 solution, or from KNO3 to NaCl? Explain briefly.
Two samples of sodium chloride solutions are brought to a boil on a stove. One of the solutions boils at 100.10C and the other at 100.15C. a Which of the solutions is more concentrated? b Which of the solutions would have a lower freezing point? c If you split the solution that boils at 100.1C into two portions, how would the boiling points of the samples compare? Which of the following statements do you agree with regarding the determination of your answer for part c? I. The question cannot be answered with certainty without knowing the volumes of each portion. II. Making the necessary assumption that the two samples have equal volumes, I was able to correctly answer the question. III. The volumes that the sample was split into are irrelevant when determining the correct answer.
When KNO3 is dissolved in water, the resulting solution is significantly colder than the water was originally. (a) Is the dissolution of KNO3 an endothermic or an exothermic process? (b) What conclusions can you draw about the intermolecular attractions involved in the process? (c) Is the resulting solution an ideal solution?
A forensic chemist is given a white solid that is suspected of being pure cocaine (C17H21NO4, molar mass = 303.35 g/mol). She dissolves 1.22 0.01 g of the solid in 15.60 0.01 g benzene. The freezing point is lowered by 1.32 0.04C. a. What is the molar mass of the substance? Assuming that the percent uncertainty in the calculated molar mass is the same as the percent uncertainty in the temperature change, calculate the uncertainty in the molar mass. b. Could the chemist unequivocally state that the substance is cocaine? For example, is the uncertainty small enough to distinguish cocaine from codeine (C18H21NO3, molar mass = 299.36 g/mol)? c. Assuming that the absolute uncertainties in the measurements of temperature and mass remain unchanged, how could the chemist improve the precision of her results?
An unknown compound contains only carbon, hydrogen, and oxygen. Combustion analysis of the compound gives mass percents of 31.57% C and 5.30% H. The molar mass is determined by measuring the freezing-point depression of an aqueous solution. A freezing point of 5.20C is recorded for a solution made by dissolving 10.56 g of the compound in 25.0 g water. Determine the empirical formula, molar mass, and molecular formula of the compound. Assume that the compound is a nonelectrolyte.
Benzyl acetate is one of the active components of oil of jasmine. If 0.125 g of the compound is added to 25.0 g of chloroform (CHCl3), the boiling point of the solution is 61.82 C. What is the molar mass of benzyl acetate?
Calculate the freezing point of 525 g of water that contains 25.0 g of NaCl. Assume i, the vant Hoff factor, is 1.85 for NaCl.
The vapor pressure of methanol, CH3OH, is 94 torr at 20 C. The vapor pressure of ethanol, C2H5OH, is 44 torr at the same temperature. (a) Calculate the mole fraction of methanol and of ethanol in a solution of 50.0 g of methanol and 50.0 g of ethanol. (b) Ethanol and methanol form a solution that behaves like an ideal solution. Calculate the vapor pressure of methanol and of ethanol above the solution at 20 C.

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