Use Maxwell relation No. 3 to evaluate - a V² VDW EOS: RT P= V-b

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
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Can you explain how he got R/V-b for the final answer?

Example: Use Maxurell relation No. 3 to evaluate (30), of at gas.
VDW.
For VDW
EOS: P =
RT
v= b
(av)T = (31) v
( 27 ) ₂ =
R
V-b
a
V²
L26
Transcribed Image Text:Example: Use Maxurell relation No. 3 to evaluate (30), of at gas. VDW. For VDW EOS: P = RT v= b (av)T = (31) v ( 27 ) ₂ = R V-b a V² L26
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