UNK -250000 -200000 -150000 100000 2 noighbors -50000 0- ref-07 8.0 7.5 7.0 6.5 6.0 5.5 5.0 4.5 4.0 3.5 3.0 2.5 2.0 1.5 1.0 0.5 0.0 -0.5 f1 (ppm) -5.02 c1.59 S6'0-
UNK -250000 -200000 -150000 100000 2 noighbors -50000 0- ref-07 8.0 7.5 7.0 6.5 6.0 5.5 5.0 4.5 4.0 3.5 3.0 2.5 2.0 1.5 1.0 0.5 0.0 -0.5 f1 (ppm) -5.02 c1.59 S6'0-
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Question
Based on the following 1H-NMR data, what is the possible structure of the alcohol C5H11OH?

Transcribed Image Text:The image shows an NMR (Nuclear Magnetic Resonance) spectrum titled "UNK" with multiple peaks representing different chemical environments in a molecule. Here’s a detailed explanation of the graph elements:
### Graph Explanation:
**Axes:**
- **Horizontal Axis (f1 ppm):** This axis represents the chemical shift in parts per million (ppm), ranging from about 8.0 to -0.5 ppm.
- **Vertical Axis (Intensity):** The intensity scale ranges from 0 to 250,000, indicating the strength of the NMR signals.
**Peak Data:**
- Peaks are labeled with specific ppm values:
- Broad peak around 6-7 ppm.
- Peaks at approximately 3.46 ppm, 2.00 ppm, 1.15 ppm, and 0.95 ppm.
- The peak at 1.15 ppm is noted with "2 neighbors."
**Additional Text Notations:**
- "ref-07" is marked near the baseline indicating a reference peak or sample.
- Chemical shift values are noted above and around the peaks:
- Around 1.74, 1.66, 1.59, 1.57, 1.49, 1.47, 1.32, 1.15, 0.95, 0.88 ppm.
- A handwritten note “2 neighbors” is seen above the 2.00 ppm peak, which typically indicates the splitting pattern for that peak.
### General Interpretation:
- This spectrum can be used to determine the structure of the molecule by analyzing the chemical shift of peaks, their intensity, and their splitting patterns.
- Higher chemical shifts (moving left) often correspond to environments with electronegative atoms or unsaturation.
- The peak splitting is indicative of the number of adjacent hydrogen atoms (neighbors).
This analysis will help in understanding the structure and characteristics of an unknown compound (labeled "UNK") in chemical research or educational contexts.
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