UNK -250000 -200000 -150000 100000 2 noighbors -50000 0- ref-07 8.0 7.5 7.0 6.5 6.0 5.5 5.0 4.5 4.0 3.5 3.0 2.5 2.0 1.5 1.0 0.5 0.0 -0.5 f1 (ppm) -5.02 c1.59 S6'0-

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question

Based on the following 1H-NMR data, what is the possible structure of the alcohol C5H11OH? 

The image shows an NMR (Nuclear Magnetic Resonance) spectrum titled "UNK" with multiple peaks representing different chemical environments in a molecule. Here’s a detailed explanation of the graph elements:

### Graph Explanation:

**Axes:**
- **Horizontal Axis (f1 ppm):** This axis represents the chemical shift in parts per million (ppm), ranging from about 8.0 to -0.5 ppm.
- **Vertical Axis (Intensity):** The intensity scale ranges from 0 to 250,000, indicating the strength of the NMR signals.

**Peak Data:**
- Peaks are labeled with specific ppm values: 
  - Broad peak around 6-7 ppm.
  - Peaks at approximately 3.46 ppm, 2.00 ppm, 1.15 ppm, and 0.95 ppm.
- The peak at 1.15 ppm is noted with "2 neighbors."

**Additional Text Notations:**
- "ref-07" is marked near the baseline indicating a reference peak or sample.
- Chemical shift values are noted above and around the peaks: 
  - Around 1.74, 1.66, 1.59, 1.57, 1.49, 1.47, 1.32, 1.15, 0.95, 0.88 ppm.
- A handwritten note “2 neighbors” is seen above the 2.00 ppm peak, which typically indicates the splitting pattern for that peak.

### General Interpretation:
- This spectrum can be used to determine the structure of the molecule by analyzing the chemical shift of peaks, their intensity, and their splitting patterns.
- Higher chemical shifts (moving left) often correspond to environments with electronegative atoms or unsaturation.
- The peak splitting is indicative of the number of adjacent hydrogen atoms (neighbors).

This analysis will help in understanding the structure and characteristics of an unknown compound (labeled "UNK") in chemical research or educational contexts.
Transcribed Image Text:The image shows an NMR (Nuclear Magnetic Resonance) spectrum titled "UNK" with multiple peaks representing different chemical environments in a molecule. Here’s a detailed explanation of the graph elements: ### Graph Explanation: **Axes:** - **Horizontal Axis (f1 ppm):** This axis represents the chemical shift in parts per million (ppm), ranging from about 8.0 to -0.5 ppm. - **Vertical Axis (Intensity):** The intensity scale ranges from 0 to 250,000, indicating the strength of the NMR signals. **Peak Data:** - Peaks are labeled with specific ppm values: - Broad peak around 6-7 ppm. - Peaks at approximately 3.46 ppm, 2.00 ppm, 1.15 ppm, and 0.95 ppm. - The peak at 1.15 ppm is noted with "2 neighbors." **Additional Text Notations:** - "ref-07" is marked near the baseline indicating a reference peak or sample. - Chemical shift values are noted above and around the peaks: - Around 1.74, 1.66, 1.59, 1.57, 1.49, 1.47, 1.32, 1.15, 0.95, 0.88 ppm. - A handwritten note “2 neighbors” is seen above the 2.00 ppm peak, which typically indicates the splitting pattern for that peak. ### General Interpretation: - This spectrum can be used to determine the structure of the molecule by analyzing the chemical shift of peaks, their intensity, and their splitting patterns. - Higher chemical shifts (moving left) often correspond to environments with electronegative atoms or unsaturation. - The peak splitting is indicative of the number of adjacent hydrogen atoms (neighbors). This analysis will help in understanding the structure and characteristics of an unknown compound (labeled "UNK") in chemical research or educational contexts.
Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 2 steps with 1 images

Blurred answer
Similar questions
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY