under theromodynamic base conditions, the below system gives alkylation at the less substituted alpha carbon. This is because HA is constrained so that it possesses no orbital with the carbonyl pi system of the carbonyl, thus the corresponding conjugate base cannot into the carbonyl and is not stabilized, thus HA is not acidic. H Ме H. Mel H. НА НА
under theromodynamic base conditions, the below system gives alkylation at the less substituted alpha carbon. This is because HA is constrained so that it possesses no orbital with the carbonyl pi system of the carbonyl, thus the corresponding conjugate base cannot into the carbonyl and is not stabilized, thus HA is not acidic. H Ме H. Mel H. НА НА
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:under theromodynamic base conditions, the below system gives alkylation at the less substituted
alpha carbon. This is because HA is constrained so that it possesses no orbital
with the carbonyl pi system of the carbonyl, thus the corresponding conjugate base cannot
into the carbonyl and is not stabilized, thus HA is not acidic.
H
Ме
NaOEt
H.
Mel
НА
НА
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