UI Wash water used 500 ml Ans. 0.4036 g. Og and 0.7000 g KBrOa are added to 250 ml of water. BrOg is collected on a filter and washed with 250 ml of g in an oven, how much does the precipitated AgBrO3 3.

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Questions number 11.12.13
vunt Cl if the losses caused by solubility in the
precipitating solution and wash water are taken into account? The conditions
of precipitation and washing are:
Final volume of precipitating solution
Excess 0.1 M AgNO3 present
Volume of wash water used
200 ml
1.0 ml
500 ml
Ans. 0.4036 g.
11. 0.5000 g AgNO3 and 0.7000 g KBRO, are added to 250 ml of water.
The precipitated AgBrO3 is collected on a filter and washed with 250 ml of
water. After drying in an oven, how much does the precipitated AgBrOs 1.7
weigh?
12. Find the milligrams of Cl- left in solution if 50 ml 0.1 M AgNO3 is
added to 200 ml of solution which contains 0.2500 g NaCl. Ans. 3 x 10-4 mg.
13. 40.00 ml 0.5000 M AgNO, is added to 230 ml of water which contains
1.942 g K,CrO4. What percentage of chromium remains unprecipitated?
Ans. 0.2%.
14. M(OH), is a slightly soluble strong base which dissolves to the extent
of 10-6 mole per 100 ml. To 200 ml of 0.1 M MSO,, solid NaOH is added.
(a) How many grams of NAOH have been added before a precipitate
begins to form?
(b) What is the pH when 75 per cent of M+2 has precipitated?
Ans. (b) 7.60.
15. The solubility of a hydroxide, X(OH)2, is 0.003 g per liter. The
molecular weight is 150.
(a) Compute the solubility product.
(b) At what pH will a precipitate begin to form if an acid solution of
0.01 M X+2 is neutralized?
added to 100 ml 0,1 M NH,
Transcribed Image Text:vunt Cl if the losses caused by solubility in the precipitating solution and wash water are taken into account? The conditions of precipitation and washing are: Final volume of precipitating solution Excess 0.1 M AgNO3 present Volume of wash water used 200 ml 1.0 ml 500 ml Ans. 0.4036 g. 11. 0.5000 g AgNO3 and 0.7000 g KBRO, are added to 250 ml of water. The precipitated AgBrO3 is collected on a filter and washed with 250 ml of water. After drying in an oven, how much does the precipitated AgBrOs 1.7 weigh? 12. Find the milligrams of Cl- left in solution if 50 ml 0.1 M AgNO3 is added to 200 ml of solution which contains 0.2500 g NaCl. Ans. 3 x 10-4 mg. 13. 40.00 ml 0.5000 M AgNO, is added to 230 ml of water which contains 1.942 g K,CrO4. What percentage of chromium remains unprecipitated? Ans. 0.2%. 14. M(OH), is a slightly soluble strong base which dissolves to the extent of 10-6 mole per 100 ml. To 200 ml of 0.1 M MSO,, solid NaOH is added. (a) How many grams of NAOH have been added before a precipitate begins to form? (b) What is the pH when 75 per cent of M+2 has precipitated? Ans. (b) 7.60. 15. The solubility of a hydroxide, X(OH)2, is 0.003 g per liter. The molecular weight is 150. (a) Compute the solubility product. (b) At what pH will a precipitate begin to form if an acid solution of 0.01 M X+2 is neutralized? added to 100 ml 0,1 M NH,
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