Two signals appear in the 1H NMR spectrum of thecompound shown here. One has twice the integration ofthe other. The signal with greater area corresponds to achemical shift of 9.3 ppm. The signal with less areacorresponds to a chemical shift of -2.9 ppm. Explain.Hint: Consider the magnetic field lines from a ring current

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Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Two signals appear in the 1H NMR spectrum of the
compound shown here. One has twice the integration of
the other. The signal with greater area corresponds to a
chemical shift of 9.3 ppm. The signal with less area
corresponds to a chemical shift of -2.9 ppm. Explain.
Hint: Consider the magnetic field lines from a ring current

Expert Solution
Step 1

Explanation:

The 12 equivalent protons outside the ring are deshielded, 6 protons inside the ring are shielded.

Organic Chemistry: Principles and Mechanisms (Second Edition), Chapter 16, Problem 16.53P , additional homework tip  1

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