### Instructions for Spectroscopy Problems**To ensure accuracy in your responses, follow these guidelines very carefully:**1. **Read the Directions Carefully:** Not following the directions may lead to incorrect answers.2. **Format Your Answers as Directed:** Incorrect formatting of your answers may result in them being marked wrong.3. **Reference Tables:** Below are the IR regions and NMR chemical shifts tables for assistance with spectroscopy problems.---### Nuclear Magnetic Resonance (NMR) Chemical Shifts#### 1H NMR (Proton NMR) Chemical Shifts:- **12 - 10 ppm:** Hydrogen atoms in carboxylic acids (R-C=O)OH and aldehydes (R-C=O)H.- **10 - 9 ppm:** Aldehyde hydrogen atoms (R-CH=O).- **8 - 7 ppm:** Aromatic protons (benzene rings).- **7 - 6 ppm:** Protons attached to carbon-carbon double bonds (C=CH).- **6 - 5 ppm:** Vinyl protons (H-C=C).- **5 - 4 ppm:** Hydrogen atoms attached to electronegative atoms such as F, Cl, Br (H-C-X), and ethers (H-C-O).- **4 - 3 ppm:** Hydrogen atoms in carbon chains with electronegative substituents.- **3 - 2 ppm:** Hydrogen atoms attached to alkynes (H-C≡C), thiols (H-C-S), and amides (H-C-N).- **2 - 1 ppm:** Hydrogen atoms in benzylic positions (H-C6H5) and methyl groups (H-C-CH3).### Infrared (IR) Spectroscopy TableThe provided IR spectroscopy table illustrates important functional group absorptions based on wavenumber (cm^-1):- **3400 - 3200 cm^-1:** - Broad absorbance range for O-H and N-H bonds. - Sharp absorbance for ≡C-H bonds.- **3200 - 3000 cm^-1:** - Absorbance due to aromatic C-H stretching. - Alkyne ≡C-H stretching is observed.- **3000 - 2850 cm^-1:** - Absorbance for sp3 C-H stretching.- **2850 - 2750 cm^-1 ### Question: Identifying Non-Part of ¹H-NMR Spectrum**Which one of the following is NOT part of a ¹H-NMR spectrum?**- [ ] Chemical Shift- [ ] Coupling Constant- [ ] Degrees of Unsaturation- [ ] Integration- [ ] Spin-Spin Splitting### Explanation of Terms in ¹H-NMR Spectrum1. **Chemical Shift**: - It represents the resonance frequency of a nucleus relative to a standard in a magnetic field. It's crucial for identifying the environment around hydrogen atoms in the molecule.2. **Coupling Constant**: - This describes the interaction between nuclear spins of neighboring hydrogen atoms. It's measured in Hertz (Hz) and provides information on the number of adjacent protons.3. **Integration**: - This indicates the relative number of hydrogen atoms responsible for each signal in the spectrum, helping determine the molecular structure.4. **Spin-Spin Splitting**: - Also known as J-coupling, it describes the splitting of NMR signals into multiple peaks due to interaction with nearby non-equivalent protons.### Incorrect Option- **Degrees of Unsaturation**: - This is not part of a ¹H-NMR spectrum. Instead, it is a concept used to calculate the number of rings and pi bonds in a molecule based on its molecular formula.This is a crucial differentiation for students and professionals using NMR spectroscopy in Organic Chemistry to analyze molecular structures accurately.

H NMR manly gives information about number of non equivalent protons in molecule

Answered: Which one of the following is NOT part…

Which one of the following is NOT part of a ¹H-NMR spectrum? O Chemical Shift Coupling Constant Degrees of Unsaturation O Integration O Spin-Spin Splitting

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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