Twist: 1H Draw the twist form of cyclohexane PART TWO: CHLOROCYCLOHEXANE 2A Draw the model of chlorocyclohexane 2B Is the chlorine axial or equatorial? 2C Draw the model of the flipped chair 2D Is the chlorine axial or equatorial? equato 2E Which conformation is more stable, the one with the chlorine axial or equatorial? 50

Twist: 1H Draw the twist form of cyclohexane PART TWO: CHLOROCYCLOHEXANE 2A Draw the model of chlorocyclohexane 2B Is the chlorine axial or equatorial? 2C Draw the model of the flipped chair 2D Is the chlorine axial or equatorial? equato 2E Which conformation is more stable, the one with the chlorine axial or equatorial? 50

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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21 Which statement is correct concerning the relative stabilities of the two conformations, A and B, below? H₂C H O A Multiple Choice O H CH₂ A is more stable. B is more stable. A and B are equal in stabilities. CH₂ H B CH₂ A and B are not equal in stability, but the preferred conformation cannot be determined by inspection.
Question 3 of 7 > O Macmillan Learning For the substituted cyclohexane compound shown, identify the atoms that are cis to the hydroxyl (OH) substituent. Br H D CI F C A C E ECH 3 H I HO GF BH Identify the atoms that are cis to the hydroxyl. G K A F H CI K HJ HI B D H J
For the compound below please identify the position of equilibrium (which chair conformation is more stable = major conformation): A CI B 0 CI CI CI CI (1r,4r)-1,4-dichlorocyclohexane CI CI CI D ći (major) (equal) CI CI cannot flip CI CI (major) CI CI CI
Organic Chem HW
Question 6
Draw the substituents in the specified locations on the given cyclohexane ring to show the most stable chair conformation. Be sure that the bonds are drawn to clearly show whether they are axial or equatorial. Substituent CH3 Position 2 3 4
NO Consider the molecule below: H₂C H3C CH₂CH3 CH₂CH3 Consider rotation around the indicated bond. [1] Draw a Newman projection for the lowest energy conformer of this molecule looking down the indicated bond. [2] Draw a Newman projection for the highest energy conformer of this molecule looking down the indicated bond. # 3 d F4 % 5 F6 00
4 Practice 2 3-9 4.8 Conformational Analysis of Butane The graph below represents the relative energies of the conformations of butane: ww B Relative energy -1- —— 0° 60° 120° 180° 240° 300° 360° Angle of rotation Select the Newman projection that corresponds with position C on the graph (an angle of rotation of 120 degrees). HA 3 H I I I I # CH3 CH 3 CH 3 CH3 -I H HH CH3 CH3 CH3 80⁰0 CH3 H I I Н 4 000 000 % 6 MacBook Air 7 8 DIL FB 9 0
01 04 02 3 Br. Hen H. Tg☀☀ H Ph Ph Br- All the above (Ph Br. Ph Bri Br 2 Ph 3 Bri Br Bri H Ph H Which of the following is the Newman projection for the following conformation? Ph Br
L 17
O Macmillan Learning AO Determine whether the conformation shown is the eclipsed or staggered Newman projection, and drag the groups to their correct locations. Leave the atoms in the wrong conformation blank. H CH3 H H CH3 H H H H Answer Bank H H MacBook Pro CH H 1 Rotate X Rotate Y BRAKEL D Rotate Z Zoom In Zoom Out A Label Atoms