#13 dimethylcyclohexaneLabel all positions as axial or equatorial11- Draw the more stable chair conformation of thefollowing moleculesa) trans-1-Chloro-3-methylcyclohexaneb) cis-1-Ethyl-2-methylcyclohexane12- How many chirality centers does morphine have?How many stereoisomers of morphine are possible inN-CH33HHHOH Hprinciple?How many chiral carbons the following molecules has?Label them with an asterisk *.CH311 HOHH 7MorphineHCH313- Classify each of the following reactions as an addition,elimination, substitution, or rearrangementa) CH₂Br + KOH → CH₂OH + KBrb) CH₂CH₂Br →→ H₂C=CH₂ + HBrc) H₂C=CH₂ + H₂ → CH₂CH₂

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13- Classify each of the following reactions as an addition, elimination, substitution, or rearrangement a) CH₂Br +KOH →→ CH₂OH + KBr b) CH₂CH₂Br → H₂C=CH₂ + HBr c) H₂C=CH₂ + H₂ → CH₂CH₂

13- Classify each of the following reactions as an addition, elimination, substitution, or rearrangement a) CH₂Br +KOH →→ CH₂OH + KBr b) CH₂CH₂Br → H₂C=CH₂ + HBr c) H₂C=CH₂ + H₂ → CH₂CH₂

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Concept explainers

Stereochemistry and Isomerism

Stereochemistry deals with the three-dimensional structure and properties of molecules. It explains the arrangement of atoms and their manipulation within a molecule in a 3D structure. Stereochemistry can be dealt with all types of molecules. Based on the stereochemistry of a molecule, the physical and chemical properties of the molecules vary.

Question

#13

dimethylcyclohexane
Label all positions as axial or equatorial
11- Draw the more stable chair conformation of the
following molecules
a) trans-1-Chloro-3-methylcyclohexane
b) cis-1-Ethyl-2-methylcyclohexane
12- How many chirality centers does morphine have?
How many stereoisomers of morphine are possible in
N
-CH3
3
H
H
HO
H H
principle?
How many chiral carbons the following molecules has?
Label them with an asterisk *.
CH3
11 H
OH
H 7
Morphine
H
CH3
13- Classify each of the following reactions as an addition,
elimination, substitution, or rearrangement
a) CH₂Br + KOH → CH₂OH + KBr
b) CH₂CH₂Br →→ H₂C=CH₂ + HBr
c) H₂C=CH₂ + H₂ → CH₂CH₂

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