Try Mixture of 2-butanol enantiomers showed a specific rotation of +6.76. What is the composition of this mixture given the specific rotation of pure (S)-(+)-2- butanol and (R)-(-)-2-butanol to be + 13.52 and -13.52 respectively. >A sample of 2-methyl-1-butanol has a specific rotation, [a]35 = + 1.151. If the specific rotation of the pure R enantiomer [a = + 5.756. (a) What is the percent enantiomeric excess of the sample? (b) Which enantiomer is in excess, the (R) or the (S)?

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Mixture of 2-butanol enantiomers showed a specific rotation of +6.76. What is
the composition of this mixture given the specific rotation of pure (S)-(+)-2-
butanol and (R)-(-)-2-butanol to be + 13.52 and -13.52 respectively.
>A sample of 2-methyl-1-butanol has a specific rotation, [a]35 = + 1.151. If the
specific rotation of the pure R enantiomer [a]3 = + 5.756. (a) What is the
percent enantiomeric excess of the sample? (b) Which enantiomer is in excess,
the (R) or the (S)?
Transcribed Image Text:Try Mixture of 2-butanol enantiomers showed a specific rotation of +6.76. What is the composition of this mixture given the specific rotation of pure (S)-(+)-2- butanol and (R)-(-)-2-butanol to be + 13.52 and -13.52 respectively. >A sample of 2-methyl-1-butanol has a specific rotation, [a]35 = + 1.151. If the specific rotation of the pure R enantiomer [a]3 = + 5.756. (a) What is the percent enantiomeric excess of the sample? (b) Which enantiomer is in excess, the (R) or the (S)?
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