Tron can be extracted from haematite, Fe,O3, using either C or CO2 as the reducing agent. The reactions are shown below. AH = +492.7 kJ /mol FezO3(s) +3 C(s) 2 Fe(s) +3 CO(g) - 2 Fe(s) + 3 CO2(g) AH = - 24.8 kJ/mol Fe;O3(s) + 3 CO(g) Substance S° (J/ K-mol) Fe2Oa (s) 87.4 Fe (s) 27.3 C (s) CO (g) CO2 (g) 5.7 197.6 213.6 Use available data given to: 1. Calculate the minimum temperature at which reduction with carbon is feasible

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Chapter1: Chemical Foundations
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2. Prove by calculation that reduction with carbon monoxide is feasible at all temperatures.
Expected Answer:
For reduction with carbon (C):
AS
+542.9 J/K-mol
T.
908 K
For reduction with carbon monoxide (CO):
AS
+15.2 J K/mol
T.
-1630 K.
Since the lowest temperature possible is 0 K, the reaction is feasible at all temperatures.
Transcribed Image Text:2. Prove by calculation that reduction with carbon monoxide is feasible at all temperatures. Expected Answer: For reduction with carbon (C): AS +542.9 J/K-mol T. 908 K For reduction with carbon monoxide (CO): AS +15.2 J K/mol T. -1630 K. Since the lowest temperature possible is 0 K, the reaction is feasible at all temperatures.
Tron can be extracted from haematite, Fe,Oa, using either C or CO2 as the reducing agent.
The reactions are shown below.
AH = +492.7 kJ /mol
%3D
Fe2O3(s) + 3 C(s) → 2 Fe(s) + 3 CO(g)
AH = - 24.8 kJ/mol
Fe2O3(s) + 3 CO(g) → 2 Fe(s) + 3 CO2(g)
Substance
S° (J/ K•mol)
Fe2O3 (s)
87.4
Fe (s)
27.3
C (s)
5.7
CO (g)
197.6
CO2 (g)
213.6
Use available data given to:
1. Calculate the minimum temperature at which reduction with carbon is feasible
446
Transcribed Image Text:Tron can be extracted from haematite, Fe,Oa, using either C or CO2 as the reducing agent. The reactions are shown below. AH = +492.7 kJ /mol %3D Fe2O3(s) + 3 C(s) → 2 Fe(s) + 3 CO(g) AH = - 24.8 kJ/mol Fe2O3(s) + 3 CO(g) → 2 Fe(s) + 3 CO2(g) Substance S° (J/ K•mol) Fe2O3 (s) 87.4 Fe (s) 27.3 C (s) 5.7 CO (g) 197.6 CO2 (g) 213.6 Use available data given to: 1. Calculate the minimum temperature at which reduction with carbon is feasible 446
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