Traces of aniline can be determined by reaction with an excess of electrolytically generated Br;: C,H;NH, + 3Br, → CH,Br,NH, + 3H + 3Br The polarity of the working electrode is then reversed, and the excess bromine is determined by a coulometric titration involving the generation of Cu(I): Br, + 2Cu+ 2Br + 2Cu²+ Suitable quantities of KBr and copper(II) sulfate were added to a 25.0-mL sample containing aniline. Calculate the mass in micrograms of C,H;NH, in the sample from the accompanying data: Generation Time (min) Working Electrode Functioning As with a Constant Current of 1.00 mA Anode 3.76 Cathode 0.270

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24-11 Traces of aniline can be determined by reaction with an excess of electrolytically generated Br,:
CH;NH, + 3Br, C,H,Br,NH, + 3H + 3Br
The polarity of the working electrode is then reversed, and the excess bromine is determined by a
coulometric titration involving the generation of Cu(I):
Br, + 2Cu*
→ 2Br + 2Cu2+
Suitable quantities of KBr and copper(II) sulfate were added to a 25.0-mL sample containing aniline.
Calculate the mass in micrograms of C,H;NH, in the sample from the accompanying data:
Generation Time (min)
Working Electrode
Functioning As
with a Constant Current
of 1.00 mA
Anode
3.76
Cathode
0.270
Transcribed Image Text:24-11 Traces of aniline can be determined by reaction with an excess of electrolytically generated Br,: CH;NH, + 3Br, C,H,Br,NH, + 3H + 3Br The polarity of the working electrode is then reversed, and the excess bromine is determined by a coulometric titration involving the generation of Cu(I): Br, + 2Cu* → 2Br + 2Cu2+ Suitable quantities of KBr and copper(II) sulfate were added to a 25.0-mL sample containing aniline. Calculate the mass in micrograms of C,H;NH, in the sample from the accompanying data: Generation Time (min) Working Electrode Functioning As with a Constant Current of 1.00 mA Anode 3.76 Cathode 0.270
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