Todine atoms combine to form molecular iodine in the gas phase I(g) + I(g) → 1₂ (g) This reaction follows second-order kinetics and has the high rate constant 7.0 x 10°/M s at 23°C. (a) If the initial concentration of I is 0.086 M, calculate the concentration after 2.0 min. (b) Calculate the half-life of the reaction if the initial concentration of I is 0.60 M and if it is 0.42 M.

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Iodine atoms combine to form molecular iodine in the gas phase
This reaction follows second-order kinetics and has the high rate constant 7.0 x 10°/M s at 23°C.
If the initial concentration of I is 0.086 M, calculate the concentration after 2.0 min.
(a)
(b) Calculate the half-life of the reaction if the initial concentration of I is 0.60 M and if it is 0.42 M.
B
Strategy
(a)
I(g) + I(g) → 12 (8)
(b)
1
1+1—h
Page 589
The relationship between the concentrations of a reactant at different times is given by the integrated rate law. Because
this is a second-order reaction, we use Equation (13.7).
We are asked to calculate the half-life. The half-life for a second-order reaction is given by Equation (13.8).
Transcribed Image Text:Iodine atoms combine to form molecular iodine in the gas phase This reaction follows second-order kinetics and has the high rate constant 7.0 x 10°/M s at 23°C. If the initial concentration of I is 0.086 M, calculate the concentration after 2.0 min. (a) (b) Calculate the half-life of the reaction if the initial concentration of I is 0.60 M and if it is 0.42 M. B Strategy (a) I(g) + I(g) → 12 (8) (b) 1 1+1—h Page 589 The relationship between the concentrations of a reactant at different times is given by the integrated rate law. Because this is a second-order reaction, we use Equation (13.7). We are asked to calculate the half-life. The half-life for a second-order reaction is given by Equation (13.8).
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