To preview image click here Choose the correct reagents for the following synthesis. 1. Correct reagent(s) for Step | [Select ] 2. Correct reagent(s) for Step II 3. Correct reagent(s) for Step III 4. Correct reagent(s) for Step IV [Select] [Select ] [Select] 11
Reactive Intermediates
In chemistry, reactive intermediates are termed as short-lived, highly reactive atoms with high energy. They rapidly transform into stable particles during a chemical reaction. In specific cases, by means of matrix isolation and at low-temperature reactive intermediates can be isolated.
Hydride Shift
A hydride shift is a rearrangement of a hydrogen atom in a carbocation that occurs to make the molecule more stable. In organic chemistry, rearrangement of the carbocation is very easily seen. This rearrangement can be because of the movement of a carbocation to attain stability in the compound. Such structural reorganization movement is called a shift within molecules. After the shifting of carbocation over the different carbon then they form structural isomers of the previous existing molecule.
Vinylic Carbocation
A carbocation where the positive charge is on the alkene carbon is known as the vinyl carbocation or vinyl cation. The empirical formula for vinyl cation is C2H3+. In the vinyl carbocation, the positive charge is on the carbon atom with the double bond therefore it is sp hybridized. It is known to be a part of various reactions, for example, electrophilic addition of alkynes and solvolysis as well. It plays the role of a reactive intermediate in these reactions.
Cycloheptatrienyl Cation
It is an aromatic carbocation having a general formula, [C7 H7]+. It is also known as the aromatic tropylium ion. Its name is derived from the molecule tropine, which is a seven membered carbon atom ring. Cycloheptatriene or tropylidene was first synthesized from tropine.
Stability of Vinyl Carbocation
Carbocations are positively charged carbon atoms. It is also known as a carbonium ion.
![To preview image click here
Choose the correct reagents for the following synthesis.
1. Correct reagent(s) for Step | [Select ]
2. Correct reagent(s) for Step II
3. Correct reagent(s) for Step III
4. Correct reagent(s) for Step IV
5. Correct reagents(s) for Step V
H
-OH
|||
[Select]
[Select]
[Select]
[Select]
[Select]
A. NH2CH(CH3)2/HCI (cat.)
B. NH2C(CH3)3/HCI (cat.)
C. NHCHCH3/HCI (cat.)
H
OMgBr
H
Y
OH
OH](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fd28bb5a8-7114-481e-95e9-134d2c6aa143%2F95d28b95-833b-46a8-bdcb-a4467ea8e97b%2Fj0io5fd_processed.jpeg&w=3840&q=75)
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