To 47.62 ml of wine were added 5 mL of concentrated KI solution and 32.11 mL of solution containing (0.7557 g KIO 3)/(100.00 mL solution). The wine+reagent mixture was acidified with 10 mL of 1 M HCI to create a known number of moles of I 2 by the reaction 10 3+ excessi+ some H*-> 31 2 Some of this I 2 immediately reacted with the sulfite in the wine sample by the reaction SO 3+12-> products we don't care about The left over I 2 was titrated to a starch end point with 10.14 mL of 0.04521 M thiosulfate solution, by the reaction 12+ 25 20 3-> products we don't care about What is the concentration of sulfite in the wine, expressed in mM?

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To 47.62 ml of wine were added 5 mL of concentrated KI solution and 32.11 mL of solution containing
(0.7557 g KIO 3)/(100.00 mL solution). The wine+reagent mixture was acidified with 10 ml of 1 M HCI to
create a known number of moles of I 2 by the reaction
10 3
+ excessl + some H*-> 31 2
Some of this I 2 immediately reacted with the sulfite in the wine sample by the reaction
SO 3 +12 --> products we don't care about
The left over I 2 was titrated to a starch end point with 10.14 mL of 0.04521 M thiosulfate solution, by the
reaction
12+ 25 20 32-> products we don't care about
What is the concentration of sulfite in the wine, expressed in mM?
Transcribed Image Text:To 47.62 ml of wine were added 5 mL of concentrated KI solution and 32.11 mL of solution containing (0.7557 g KIO 3)/(100.00 mL solution). The wine+reagent mixture was acidified with 10 ml of 1 M HCI to create a known number of moles of I 2 by the reaction 10 3 + excessl + some H*-> 31 2 Some of this I 2 immediately reacted with the sulfite in the wine sample by the reaction SO 3 +12 --> products we don't care about The left over I 2 was titrated to a starch end point with 10.14 mL of 0.04521 M thiosulfate solution, by the reaction 12+ 25 20 32-> products we don't care about What is the concentration of sulfite in the wine, expressed in mM?
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