Titanium and vanadium form colored complexes when treated with hydrogen peroxide in 1 M sulfuric acid. The titanium complex has an absorption maximum at 415 nm, and the vanadium complex has an absorption maximum at 455 nm. A 1.00 × 10−3 M solution of the titanium complex exhibits absorbance of 0.816 at 415 nm and of 0.485 at 455 nm while a 2.00 × 10−3 M solution of the vanadium complex exhibits absorbances of 0.425 and 0.608 at 415 and 455 nm, respectively. A 1.000-g sample of an alloy containing titanium and vanadium was dissolved, treated with excess hydrogen peroxide, and diluted to a final volume of 1000 mL. The absorbance of the solution was 0.697 at 415 nm and 0.533 at 455nm. Calculate: a) The concentration of titanium and vanadium in the sample. b) The percentages of titanium and vanadium in the alloy

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question

Titanium and vanadium form colored complexes when treated with hydrogen peroxide in 1 M sulfuric acid. The titanium complex has an absorption maximum at 415 nm, and the vanadium complex has an absorption maximum at 455 nm. A 1.00 × 10−3 M solution of
the titanium complex exhibits absorbance of 0.816 at 415 nm and of 0.485 at 455 nm while a 2.00 × 10−3 M solution of the vanadium complex exhibits absorbances of 0.425 and 0.608 at 415 and 455 nm, respectively. A 1.000-g sample of an alloy containing titanium and vanadium was dissolved, treated with excess hydrogen peroxide, and diluted to a final
volume of 1000 mL. The absorbance of the solution was 0.697 at 415 nm and 0.533 at 455nm. Calculate:

a) The concentration of titanium and vanadium in the sample.

b) The percentages of titanium and vanadium in the alloy.

Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 2 steps

Blurred answer
Knowledge Booster
Coordination Complexes
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY