Halide complexes of metal M of the form [MX,] are found to be stable in aqueous solution. But it is possible that they undergo rapid ligand exchange with water (or other ligands) that is not detectable because the complexes are less stable. This property is referred to as their lability. Suggest an experiment to measure the lability of these complexes that does not employ radioactive labels.

Halide complexes of metal M of the form [MX,] are found to be stable in aqueous solution. But it is possible that they undergo rapid ligand exchange with water (or other ligands) that is not detectable because the complexes are less stable. This property is referred to as their lability. Suggest an experiment to measure the lability of these complexes that does not employ radioactive labels.

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Question

Halide complexes of metal M of the form [MX,] are found to be
stable in aqueous solution. But it is possible that they undergo rapid
ligand exchange with water (or other ligands) that is not detectable
because the complexes are less stable. This property is referred to
as their lability. Suggest an experiment to measure the lability of
these complexes that does not employ radioactive labels.

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