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This question has several parts that must be completed sequentially. Derivation Look up the values of E° for the following half-cell reactions. Ag+ + e - Ag AgBr + e- - Ag + Br- Describe how you would use these values to determine the solubility product (Ksp) of AgBr at 25.0°C. Step 1 of 4 Recall and write the equilibrium expression for the Ksp of AgBr. (Subscripts and superscripts that include letters must be enclosed in braces {}.) chemPad O Help Greek k_sp=[Ag*][Br] k_sp=[Ag^+][Br^-] Your answer contains an improperly or incompletely formatted chemical formula. Your answer contains improper superscript or subscript formatting.

This question has several parts that must be completed sequentially. Derivation Look up the values of E° for the following half-cell reactions. Ag+ + e - Ag AgBr + e- - Ag + Br- Describe how you would use these values to determine the solubility product (Ksp) of AgBr at 25.0°C. Step 1 of 4 Recall and write the equilibrium expression for the Ksp of AgBr. (Subscripts and superscripts that include letters must be enclosed in braces {}.) chemPad O Help Greek k_sp=[Ag*][Br] k_sp=[Ag^+][Br^-] Your answer contains an improperly or incompletely formatted chemical formula. Your answer contains improper superscript or subscript formatting.

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Standard Electrode Potentials half-reaction E° (V) half-reaction E° (V) Hg²*(aq) + 2 e¯ → Hg(1) ClO"(aq) + H20(1) + 2 e¯ → Cl¯(aq) + 2 OH¯(aq) Ag°(aq) + e¯ → Ag(s) Hg2*(aq) + 2 e → 2 Hg(1) Fe**(aq) + e¯ → Fe²*(aq) 2 NO(g) + H20(1) + 2 e¯ → N20(g) + 2 OH¯(aq) 02(g) + 2 H*(aq) + 2 e¯→ H202(aq) F2(g) + 2 е — 2F (aq) 03(g) + 2 H*(aq) + 2 e¯ → 02(g) + H20(1) +2.87 -> +0.851 +2.076 +0.841 Со (ag) + e — ► Co²* *(aq) +1.92 +0.800 Н.0-(аq) + 2 H'(aq) + 2 е' > 2 Н,0() +1.776 +0.797 Ce*(aq) + e¯ → Ce*(aq) PbO2(s) + SO, (aq) + 4 H* (aq) + 2 e MnO4¯(aq) + 4 H*(aq) + 3 e¯ → MnO2(s) + 2 H20(1) 2 HCIO(aq) + 2 H*(aq) + 2 e¯ → 2 NO(g) + 2 H*(aq) + 2 e¯ → N20(g) + H20(1) Mn*(aq) + e¯ → Mn²*(aq) Mn04 (aq) + 8 Hн"(аq) + 5 е — Au**(aq) + 3 e¯ → Au(s) HCIO (aq) + H"(aq) + 2 e — СГ (аq) + H,0() 2 ClO3¯(aq) + 12 H*(aq) + 10 e¯ PbO2(s) + 4 H*(aq) + 2 e¯ → Cl2(g) + 2 e¯ → 2 Cl¯(aq) HCrO4¯(aq) + 7 H*(aq) + 3 e¯ → Cr*(aq) + 4 H20(1) 2 HNO2(aq) + 4 H*(aq) + 4 e¯ → N,0(g) + 3 H,0(1) TI³*(aq) + 2 e¯ → TI*(aq) Cr,0, (aq) + 14 H*(aq) + 6 e¯ → 2 Cr* (aq) + 7 H20(1) 02(g) + 4 H*(aq) + 4 e¯ → 2 H20(1) Mn02(s) + 4 H*(aq) + 2 e¯ → ClO, (aq) + 3 H*(aq) + 2 e¯ → HC1O2(aq) + H20(1) ClO, (aq) + 2 H*(aq) + 2 e¯ → Cl03 (aq) + H20(1) CIО3 (аq) + 2 Н"(ад) + е —> +1.72 +0.771 PBSO4(s) + 2 H20(1) +1.691 +0.760 +1.679 +0.695 Cl2(g) + 2 H20(1) +1.611 ClO3 (aq) + 3 H,0(1) + 6 e¯ → Cl¯(aq) + 6 OH¯(aq) MnO4¯(aq) + 2 H20(1) + 3 e S-06 (aq) + 4 H"(аq) + 2 е — 2 H-SO;(aq) I3 (aq) + 2 e¯ → 3 I (aq) 1,(s) + 2 е — 2 (aq) +0.620 +1.591 MnO2(s) + 4 OH (aq) +0.595 +1.54 +0.564 Mn²*(aq) + 4 H20(1) +0.536 +1.507 +1.498 +0.536 Cu'(aq) + e¯ → Cu(s) 02(g) + 2 H20(1) + 4 e¯ → 4 OH¯(aq) +1.482 +0.521 > Cl2(g) + 6 H20(l) Pb²*(aq) + 2 H20(1) +1.470 +0.401 Fe(CN),“(aq) + e → Fe(CN),*(aq) ClO, (aq) + H20(1) + 2 e¯ → Cu²*(aq) + 2 e¯ → Cu(s) Hg,Cl,(s) + 2 e¯ → 2 Hg(1) + 2 CI¯(aq) PbO2(s) + H20(1) + 2 e¯ → Pb0(s) + 2 OH¯(aq) AgCl(s) + e¯ → Ag(s) + Cl¯(aq) so,² (aq) + 4 H*(aq) + 2 e¯ → H2SO3(aq) + H20(1) Cu*(aq) + e¯ → Cu°(aq) Sn**(aq) + 2 e¯ → Sn²*(aq) 2 NO2 (aq) + 3 H20(1) + 4 e¯ → N20(g) + 6 OH¯(aq) S,0, (aq) + 2 e → 2 S,03² (aq) AgBr(s) + e¯ → Ag(s) + Br¯(aq) NO3 (aq) + H20(1) + 2 e 2 H*(aq) + 2 e¯ → H2(g) +1.455 +0.36 +1.36 — СIО3 (аq) + 2 он (аq) +0.360 +1.350 +0.342 +1.297 +0.268 +1.252 +0.247 +1.23 +0.222 +1.229 +0.172 Mn²*(aq) + 2 H20(1) +1.224 +0.153 +1.214 +0.151 +1.189 +0.150 ClO2(g) + H20(1) +1.152 +0.080 Br2(aq) + 2 e → 2 Br¯(aq) Br2(1) + 2 e → 2 Br¯(aq) N204(g) + 2 H*(aq) + 2 e¯ → +1.087 +0.0713 +1.066 NO2 (aq) + 2 OH¯(aq) +0.010 2 ΗΝΟ, (ag) N204(g) + 4 H*(aq) + 4 e¯ → 2 NO(g) + 2 H20(1) NO(g) + H20(1) → NO(g) + 2 H20(1) +1.065 +1.035 + H*(aq) + e –→ HNO2(aq) NO3 (aq) + 4 H"(аq) + 3 е 2 Hg**(aq) + 2 e¯ → Hg,*(aq) N204(g) + 2 e¯ → +0.983 +0.957 +0.92 2 NO, (aq) +0.867
Transcribed Image Text:Standard Electrode Potentials half-reaction E° (V) half-reaction E° (V) Hg²*(aq) + 2 e¯ → Hg(1) ClO"(aq) + H20(1) + 2 e¯ → Cl¯(aq) + 2 OH¯(aq) Ag°(aq) + e¯ → Ag(s) Hg2*(aq) + 2 e → 2 Hg(1) Fe**(aq) + e¯ → Fe²*(aq) 2 NO(g) + H20(1) + 2 e¯ → N20(g) + 2 OH¯(aq) 02(g) + 2 H*(aq) + 2 e¯→ H202(aq) F2(g) + 2 е — 2F (aq) 03(g) + 2 H*(aq) + 2 e¯ → 02(g) + H20(1) +2.87 -> +0.851 +2.076 +0.841 Со (ag) + e — ► Co²* *(aq) +1.92 +0.800 Н.0-(аq) + 2 H'(aq) + 2 е' > 2 Н,0() +1.776 +0.797 Ce*(aq) + e¯ → Ce*(aq) PbO2(s) + SO, (aq) + 4 H* (aq) + 2 e MnO4¯(aq) + 4 H*(aq) + 3 e¯ → MnO2(s) + 2 H20(1) 2 HCIO(aq) + 2 H*(aq) + 2 e¯ → 2 NO(g) + 2 H*(aq) + 2 e¯ → N20(g) + H20(1) Mn*(aq) + e¯ → Mn²*(aq) Mn04 (aq) + 8 Hн"(аq) + 5 е — Au**(aq) + 3 e¯ → Au(s) HCIO (aq) + H"(aq) + 2 e — СГ (аq) + H,0() 2 ClO3¯(aq) + 12 H*(aq) + 10 e¯ PbO2(s) + 4 H*(aq) + 2 e¯ → Cl2(g) + 2 e¯ → 2 Cl¯(aq) HCrO4¯(aq) + 7 H*(aq) + 3 e¯ → Cr*(aq) + 4 H20(1) 2 HNO2(aq) + 4 H*(aq) + 4 e¯ → N,0(g) + 3 H,0(1) TI³*(aq) + 2 e¯ → TI*(aq) Cr,0, (aq) + 14 H*(aq) + 6 e¯ → 2 Cr* (aq) + 7 H20(1) 02(g) + 4 H*(aq) + 4 e¯ → 2 H20(1) Mn02(s) + 4 H*(aq) + 2 e¯ → ClO, (aq) + 3 H*(aq) + 2 e¯ → HC1O2(aq) + H20(1) ClO, (aq) + 2 H*(aq) + 2 e¯ → Cl03 (aq) + H20(1) CIО3 (аq) + 2 Н"(ад) + е —> +1.72 +0.771 PBSO4(s) + 2 H20(1) +1.691 +0.760 +1.679 +0.695 Cl2(g) + 2 H20(1) +1.611 ClO3 (aq) + 3 H,0(1) + 6 e¯ → Cl¯(aq) + 6 OH¯(aq) MnO4¯(aq) + 2 H20(1) + 3 e S-06 (aq) + 4 H"(аq) + 2 е — 2 H-SO;(aq) I3 (aq) + 2 e¯ → 3 I (aq) 1,(s) + 2 е — 2 (aq) +0.620 +1.591 MnO2(s) + 4 OH (aq) +0.595 +1.54 +0.564 Mn²*(aq) + 4 H20(1) +0.536 +1.507 +1.498 +0.536 Cu'(aq) + e¯ → Cu(s) 02(g) + 2 H20(1) + 4 e¯ → 4 OH¯(aq) +1.482 +0.521 > Cl2(g) + 6 H20(l) Pb²*(aq) + 2 H20(1) +1.470 +0.401 Fe(CN),“(aq) + e → Fe(CN),*(aq) ClO, (aq) + H20(1) + 2 e¯ → Cu²*(aq) + 2 e¯ → Cu(s) Hg,Cl,(s) + 2 e¯ → 2 Hg(1) + 2 CI¯(aq) PbO2(s) + H20(1) + 2 e¯ → Pb0(s) + 2 OH¯(aq) AgCl(s) + e¯ → Ag(s) + Cl¯(aq) so,² (aq) + 4 H*(aq) + 2 e¯ → H2SO3(aq) + H20(1) Cu*(aq) + e¯ → Cu°(aq) Sn**(aq) + 2 e¯ → Sn²*(aq) 2 NO2 (aq) + 3 H20(1) + 4 e¯ → N20(g) + 6 OH¯(aq) S,0, (aq) + 2 e → 2 S,03² (aq) AgBr(s) + e¯ → Ag(s) + Br¯(aq) NO3 (aq) + H20(1) + 2 e 2 H*(aq) + 2 e¯ → H2(g) +1.455 +0.36 +1.36 — СIО3 (аq) + 2 он (аq) +0.360 +1.350 +0.342 +1.297 +0.268 +1.252 +0.247 +1.23 +0.222 +1.229 +0.172 Mn²*(aq) + 2 H20(1) +1.224 +0.153 +1.214 +0.151 +1.189 +0.150 ClO2(g) + H20(1) +1.152 +0.080 Br2(aq) + 2 e → 2 Br¯(aq) Br2(1) + 2 e → 2 Br¯(aq) N204(g) + 2 H*(aq) + 2 e¯ → +1.087 +0.0713 +1.066 NO2 (aq) + 2 OH¯(aq) +0.010 2 ΗΝΟ, (ag) N204(g) + 4 H*(aq) + 4 e¯ → 2 NO(g) + 2 H20(1) NO(g) + H20(1) → NO(g) + 2 H20(1) +1.065 +1.035 + H*(aq) + e –→ HNO2(aq) NO3 (aq) + 4 H"(аq) + 3 е 2 Hg**(aq) + 2 e¯ → Hg,*(aq) N204(g) + 2 e¯ → +0.983 +0.957 +0.92 2 NO, (aq) +0.867
This question has several parts that must be completed sequentially. Derivation Look up the values of E0 for the following half-cell reactions. Ag+ + e - Ag AgBr + e- - Ag + Br- Describe how you would use these values to determine the solubility product (Ksp) of AgBr at 25.0°C. Step 1 of 4 Recall and write the equilibrium expression for the Ksp of AgBr. (Subscripts and superscripts that include letters must be enclosed in braces {}.) chemPad Help Greek - k_sp=[Ag+][Br] k_sp=[Ag^+][Br^-] Your answer contains an improperly or incompletely formatted chemical formula. Your answer contains improper superscript or subscript formatting.
Transcribed Image Text:This question has several parts that must be completed sequentially. Derivation Look up the values of E0 for the following half-cell reactions. Ag+ + e - Ag AgBr + e- - Ag + Br- Describe how you would use these values to determine the solubility product (Ksp) of AgBr at 25.0°C. Step 1 of 4 Recall and write the equilibrium expression for the Ksp of AgBr. (Subscripts and superscripts that include letters must be enclosed in braces {}.) chemPad Help Greek - k_sp=[Ag+][Br] k_sp=[Ag^+][Br^-] Your answer contains an improperly or incompletely formatted chemical formula. Your answer contains improper superscript or subscript formatting.
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