This question has several parts that must be completed sequentially. Derivation Look up the values of E° for the following half-cell reactions. Ag+ + e - Ag AgBr + e- - Ag + Br- Describe how you would use these values to determine the solubility product (Ksp) of AgBr at 25.0°C. Step 1 of 4 Recall and write the equilibrium expression for the Ksp of AgBr. (Subscripts and superscripts that include letters must be enclosed in braces {}.) chemPad O Help Greek k_sp=[Ag*][Br] k_sp=[Ag^+][Br^-] Your answer contains an improperly or incompletely formatted chemical formula. Your answer contains improper superscript or subscript formatting.

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question
Standard Electrode Potentials
half-reaction
E° (V)
half-reaction
E° (V)
Hg²*(aq) + 2 e¯ → Hg(1)
ClO"(aq) + H20(1) + 2 e¯ → Cl¯(aq) + 2 OH¯(aq)
Ag°(aq) + e¯ → Ag(s)
Hg2*(aq) + 2 e → 2 Hg(1)
Fe**(aq) + e¯ → Fe²*(aq)
2 NO(g) + H20(1) + 2 e¯ → N20(g) + 2 OH¯(aq)
02(g) + 2 H*(aq) + 2 e¯→ H202(aq)
F2(g) + 2 е — 2F (aq)
03(g) + 2 H*(aq) + 2 e¯ → 02(g) + H20(1)
+2.87
->
+0.851
+2.076
+0.841
Со (ag) + e —
► Co²*
*(aq)
+1.92
+0.800
Н.0-(аq) + 2 H'(aq) + 2 е' > 2 Н,0()
+1.776
+0.797
Ce*(aq) + e¯ → Ce*(aq)
PbO2(s) + SO, (aq) + 4 H* (aq) + 2 e
MnO4¯(aq) + 4 H*(aq) + 3 e¯ → MnO2(s) + 2 H20(1)
2 HCIO(aq) + 2 H*(aq) + 2 e¯ →
2 NO(g) + 2 H*(aq) + 2 e¯ → N20(g) + H20(1)
Mn*(aq) + e¯ → Mn²*(aq)
Mn04 (aq) + 8 Hн"(аq) + 5 е —
Au**(aq) + 3 e¯ → Au(s)
HCIO (aq) + H"(aq) + 2 e — СГ (аq) + H,0()
2 ClO3¯(aq) + 12 H*(aq) + 10 e¯
PbO2(s) + 4 H*(aq) + 2 e¯ →
Cl2(g) + 2 e¯ → 2 Cl¯(aq)
HCrO4¯(aq) + 7 H*(aq) + 3 e¯ → Cr*(aq) + 4 H20(1)
2 HNO2(aq) + 4 H*(aq) + 4 e¯ → N,0(g) + 3 H,0(1)
TI³*(aq) + 2 e¯ → TI*(aq)
Cr,0, (aq) + 14 H*(aq) + 6 e¯ → 2 Cr* (aq) + 7 H20(1)
02(g) + 4 H*(aq) + 4 e¯ → 2 H20(1)
Mn02(s) + 4 H*(aq) + 2 e¯ →
ClO, (aq) + 3 H*(aq) + 2 e¯ → HC1O2(aq) + H20(1)
ClO, (aq) + 2 H*(aq) + 2 e¯ → Cl03 (aq) + H20(1)
CIО3 (аq) + 2 Н"(ад) + е —>
+1.72
+0.771
PBSO4(s) + 2 H20(1)
+1.691
+0.760
+1.679
+0.695
Cl2(g) + 2 H20(1)
+1.611
ClO3 (aq) + 3 H,0(1) + 6 e¯ → Cl¯(aq) + 6 OH¯(aq)
MnO4¯(aq) + 2 H20(1) + 3 e
S-06 (aq) + 4 H"(аq) + 2 е — 2 H-SO;(aq)
I3 (aq) + 2 e¯ → 3 I (aq)
1,(s) + 2 е — 2 (aq)
+0.620
+1.591
MnO2(s) + 4 OH (aq)
+0.595
+1.54
+0.564
Mn²*(aq) + 4 H20(1)
+0.536
+1.507
+1.498
+0.536
Cu'(aq) + e¯
→ Cu(s)
02(g) + 2 H20(1) + 4 e¯ → 4 OH¯(aq)
+1.482
+0.521
> Cl2(g) + 6 H20(l)
Pb²*(aq) + 2 H20(1)
+1.470
+0.401
Fe(CN),“(aq) + e → Fe(CN),*(aq)
ClO, (aq) + H20(1) + 2 e¯ →
Cu²*(aq) + 2 e¯ → Cu(s)
Hg,Cl,(s) + 2 e¯ → 2 Hg(1) + 2 CI¯(aq)
PbO2(s) + H20(1) + 2 e¯ → Pb0(s) + 2 OH¯(aq)
AgCl(s) + e¯ → Ag(s) + Cl¯(aq)
so,² (aq) + 4 H*(aq) + 2 e¯ → H2SO3(aq) + H20(1)
Cu*(aq) + e¯ → Cu°(aq)
Sn**(aq) + 2 e¯ → Sn²*(aq)
2 NO2 (aq) + 3 H20(1) + 4 e¯ → N20(g) + 6 OH¯(aq)
S,0, (aq) + 2 e → 2 S,03² (aq)
AgBr(s) + e¯ → Ag(s) + Br¯(aq)
NO3 (aq) + H20(1) + 2 e
2 H*(aq) + 2 e¯ → H2(g)
+1.455
+0.36
+1.36
— СIО3 (аq) + 2 он (аq)
+0.360
+1.350
+0.342
+1.297
+0.268
+1.252
+0.247
+1.23
+0.222
+1.229
+0.172
Mn²*(aq) + 2 H20(1)
+1.224
+0.153
+1.214
+0.151
+1.189
+0.150
ClO2(g) + H20(1)
+1.152
+0.080
Br2(aq) + 2 e → 2 Br¯(aq)
Br2(1) + 2 e → 2 Br¯(aq)
N204(g) + 2 H*(aq) + 2 e¯ →
+1.087
+0.0713
+1.066
NO2 (aq) + 2 OH¯(aq)
+0.010
2 ΗΝΟ, (ag)
N204(g) + 4 H*(aq) + 4 e¯ → 2 NO(g) + 2 H20(1)
NO(g) + H20(1)
→ NO(g) + 2 H20(1)
+1.065
+1.035
+ H*(aq) + e –→
HNO2(aq)
NO3 (aq) + 4 H"(аq) + 3 е
2 Hg**(aq) + 2 e¯ → Hg,*(aq)
N204(g) + 2 e¯ →
+0.983
+0.957
+0.92
2 NO, (aq)
+0.867
Transcribed Image Text:Standard Electrode Potentials half-reaction E° (V) half-reaction E° (V) Hg²*(aq) + 2 e¯ → Hg(1) ClO"(aq) + H20(1) + 2 e¯ → Cl¯(aq) + 2 OH¯(aq) Ag°(aq) + e¯ → Ag(s) Hg2*(aq) + 2 e → 2 Hg(1) Fe**(aq) + e¯ → Fe²*(aq) 2 NO(g) + H20(1) + 2 e¯ → N20(g) + 2 OH¯(aq) 02(g) + 2 H*(aq) + 2 e¯→ H202(aq) F2(g) + 2 е — 2F (aq) 03(g) + 2 H*(aq) + 2 e¯ → 02(g) + H20(1) +2.87 -> +0.851 +2.076 +0.841 Со (ag) + e — ► Co²* *(aq) +1.92 +0.800 Н.0-(аq) + 2 H'(aq) + 2 е' > 2 Н,0() +1.776 +0.797 Ce*(aq) + e¯ → Ce*(aq) PbO2(s) + SO, (aq) + 4 H* (aq) + 2 e MnO4¯(aq) + 4 H*(aq) + 3 e¯ → MnO2(s) + 2 H20(1) 2 HCIO(aq) + 2 H*(aq) + 2 e¯ → 2 NO(g) + 2 H*(aq) + 2 e¯ → N20(g) + H20(1) Mn*(aq) + e¯ → Mn²*(aq) Mn04 (aq) + 8 Hн"(аq) + 5 е — Au**(aq) + 3 e¯ → Au(s) HCIO (aq) + H"(aq) + 2 e — СГ (аq) + H,0() 2 ClO3¯(aq) + 12 H*(aq) + 10 e¯ PbO2(s) + 4 H*(aq) + 2 e¯ → Cl2(g) + 2 e¯ → 2 Cl¯(aq) HCrO4¯(aq) + 7 H*(aq) + 3 e¯ → Cr*(aq) + 4 H20(1) 2 HNO2(aq) + 4 H*(aq) + 4 e¯ → N,0(g) + 3 H,0(1) TI³*(aq) + 2 e¯ → TI*(aq) Cr,0, (aq) + 14 H*(aq) + 6 e¯ → 2 Cr* (aq) + 7 H20(1) 02(g) + 4 H*(aq) + 4 e¯ → 2 H20(1) Mn02(s) + 4 H*(aq) + 2 e¯ → ClO, (aq) + 3 H*(aq) + 2 e¯ → HC1O2(aq) + H20(1) ClO, (aq) + 2 H*(aq) + 2 e¯ → Cl03 (aq) + H20(1) CIО3 (аq) + 2 Н"(ад) + е —> +1.72 +0.771 PBSO4(s) + 2 H20(1) +1.691 +0.760 +1.679 +0.695 Cl2(g) + 2 H20(1) +1.611 ClO3 (aq) + 3 H,0(1) + 6 e¯ → Cl¯(aq) + 6 OH¯(aq) MnO4¯(aq) + 2 H20(1) + 3 e S-06 (aq) + 4 H"(аq) + 2 е — 2 H-SO;(aq) I3 (aq) + 2 e¯ → 3 I (aq) 1,(s) + 2 е — 2 (aq) +0.620 +1.591 MnO2(s) + 4 OH (aq) +0.595 +1.54 +0.564 Mn²*(aq) + 4 H20(1) +0.536 +1.507 +1.498 +0.536 Cu'(aq) + e¯ → Cu(s) 02(g) + 2 H20(1) + 4 e¯ → 4 OH¯(aq) +1.482 +0.521 > Cl2(g) + 6 H20(l) Pb²*(aq) + 2 H20(1) +1.470 +0.401 Fe(CN),“(aq) + e → Fe(CN),*(aq) ClO, (aq) + H20(1) + 2 e¯ → Cu²*(aq) + 2 e¯ → Cu(s) Hg,Cl,(s) + 2 e¯ → 2 Hg(1) + 2 CI¯(aq) PbO2(s) + H20(1) + 2 e¯ → Pb0(s) + 2 OH¯(aq) AgCl(s) + e¯ → Ag(s) + Cl¯(aq) so,² (aq) + 4 H*(aq) + 2 e¯ → H2SO3(aq) + H20(1) Cu*(aq) + e¯ → Cu°(aq) Sn**(aq) + 2 e¯ → Sn²*(aq) 2 NO2 (aq) + 3 H20(1) + 4 e¯ → N20(g) + 6 OH¯(aq) S,0, (aq) + 2 e → 2 S,03² (aq) AgBr(s) + e¯ → Ag(s) + Br¯(aq) NO3 (aq) + H20(1) + 2 e 2 H*(aq) + 2 e¯ → H2(g) +1.455 +0.36 +1.36 — СIО3 (аq) + 2 он (аq) +0.360 +1.350 +0.342 +1.297 +0.268 +1.252 +0.247 +1.23 +0.222 +1.229 +0.172 Mn²*(aq) + 2 H20(1) +1.224 +0.153 +1.214 +0.151 +1.189 +0.150 ClO2(g) + H20(1) +1.152 +0.080 Br2(aq) + 2 e → 2 Br¯(aq) Br2(1) + 2 e → 2 Br¯(aq) N204(g) + 2 H*(aq) + 2 e¯ → +1.087 +0.0713 +1.066 NO2 (aq) + 2 OH¯(aq) +0.010 2 ΗΝΟ, (ag) N204(g) + 4 H*(aq) + 4 e¯ → 2 NO(g) + 2 H20(1) NO(g) + H20(1) → NO(g) + 2 H20(1) +1.065 +1.035 + H*(aq) + e –→ HNO2(aq) NO3 (aq) + 4 H"(аq) + 3 е 2 Hg**(aq) + 2 e¯ → Hg,*(aq) N204(g) + 2 e¯ → +0.983 +0.957 +0.92 2 NO, (aq) +0.867
This question has several parts that must be completed sequentially.
Derivation
Look up the values of E0 for the following half-cell reactions.
Ag+ + e -
Ag
AgBr + e- - Ag + Br-
Describe how you would use these values to determine the solubility product (Ksp) of AgBr at 25.0°C.
Step 1 of 4
Recall and write the equilibrium expression for the Ksp of AgBr. (Subscripts and superscripts that include letters must be enclosed in braces {}.)
chemPad
Help
Greek -
k_sp=[Ag+][Br]
k_sp=[Ag^+][Br^-]
Your answer contains an improperly or incompletely formatted chemical formula. Your answer contains improper superscript or subscript formatting.
Transcribed Image Text:This question has several parts that must be completed sequentially. Derivation Look up the values of E0 for the following half-cell reactions. Ag+ + e - Ag AgBr + e- - Ag + Br- Describe how you would use these values to determine the solubility product (Ksp) of AgBr at 25.0°C. Step 1 of 4 Recall and write the equilibrium expression for the Ksp of AgBr. (Subscripts and superscripts that include letters must be enclosed in braces {}.) chemPad Help Greek - k_sp=[Ag+][Br] k_sp=[Ag^+][Br^-] Your answer contains an improperly or incompletely formatted chemical formula. Your answer contains improper superscript or subscript formatting.
Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 2 steps with 2 images

Blurred answer
Knowledge Booster
Electrolysis
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY