This molecule is able to undergo the following thermal reaction. END D O,N D. NO, b) name the reaction type, c) illustrate the control of the reaction by the frontier orbital d) comment on the stereochemical result (Absolute configurations, optical activity.
This molecule is able to undergo the following thermal reaction. END D O,N D. NO, b) name the reaction type, c) illustrate the control of the reaction by the frontier orbital d) comment on the stereochemical result (Absolute configurations, optical activity.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Question
![This molecule is able to undergo the following thermal reaction.
H.
END
D
O,N
D.
D.
NO,
b) name the reaction type,
c) illustrate the control of the reaction by the frontier orbital
d) comment on the stereochemical result (Absolute configurations, optical activity..)
e) Draw the resulting molecule showing the correct stereochemistry
o wa
be](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fdf601153-bfca-4ef3-9062-0c2690d6cc80%2F58ba3341-3444-42ff-8378-81b823caabb6%2Finioh5h_processed.jpeg&w=3840&q=75)
Transcribed Image Text:This molecule is able to undergo the following thermal reaction.
H.
END
D
O,N
D.
D.
NO,
b) name the reaction type,
c) illustrate the control of the reaction by the frontier orbital
d) comment on the stereochemical result (Absolute configurations, optical activity..)
e) Draw the resulting molecule showing the correct stereochemistry
o wa
be
![The compound shown below includes a conjugated r-system.
a) Ose the table to draw qualitative pictures off all Hückel MO's and calculate the total
electron energy of the molecule.
H
H.
D
O,N
D
*- Orbital:
c1
c2
03
04
c5
1.802
0.2319
0.4179
0.5211
0.5211
0.4179
0.2319
42
1.247
0.4179
0.5211
0.2319
0.5211
0.4179
-0.2319
43
0.445
0.5211
0.2319
-0.4179
-0.4179
0.5211
0.2319
4
-0.445
0.5211
-0.2319
-0.5211
-0.4179
0.4179
0.2319
0.5211
45
-1.247
0.4179
0.2319
0.2319
0.2319
-0.5211
0.4179
-1.802
-0.4179
0.5211
-0.5211
0.4179
-0.2319](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fdf601153-bfca-4ef3-9062-0c2690d6cc80%2F58ba3341-3444-42ff-8378-81b823caabb6%2Frvqmo6_processed.jpeg&w=3840&q=75)
Transcribed Image Text:The compound shown below includes a conjugated r-system.
a) Ose the table to draw qualitative pictures off all Hückel MO's and calculate the total
electron energy of the molecule.
H
H.
D
O,N
D
*- Orbital:
c1
c2
03
04
c5
1.802
0.2319
0.4179
0.5211
0.5211
0.4179
0.2319
42
1.247
0.4179
0.5211
0.2319
0.5211
0.4179
-0.2319
43
0.445
0.5211
0.2319
-0.4179
-0.4179
0.5211
0.2319
4
-0.445
0.5211
-0.2319
-0.5211
-0.4179
0.4179
0.2319
0.5211
45
-1.247
0.4179
0.2319
0.2319
0.2319
-0.5211
0.4179
-1.802
-0.4179
0.5211
-0.5211
0.4179
-0.2319
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