This molecule is able to undergo the following thermal reaction. END D O,N D. NO, b) name the reaction type, c) illustrate the control of the reaction by the frontier orbital d) comment on the stereochemical result (Absolute configurations, optical activity.

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Chapter1: Chemical Foundations
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This molecule is able to undergo the following thermal reaction.
H.
END
D
O,N
D.
D.
NO,
b) name the reaction type,
c) illustrate the control of the reaction by the frontier orbital
d) comment on the stereochemical result (Absolute configurations, optical activity..)
e) Draw the resulting molecule showing the correct stereochemistry
o wa
be
Transcribed Image Text:This molecule is able to undergo the following thermal reaction. H. END D O,N D. D. NO, b) name the reaction type, c) illustrate the control of the reaction by the frontier orbital d) comment on the stereochemical result (Absolute configurations, optical activity..) e) Draw the resulting molecule showing the correct stereochemistry o wa be
The compound shown below includes a conjugated r-system.
a) Ose the table to draw qualitative pictures off all Hückel MO's and calculate the total
electron energy of the molecule.
H
H.
D
O,N
D
*- Orbital:
c1
c2
03
04
c5
1.802
0.2319
0.4179
0.5211
0.5211
0.4179
0.2319
42
1.247
0.4179
0.5211
0.2319
0.5211
0.4179
-0.2319
43
0.445
0.5211
0.2319
-0.4179
-0.4179
0.5211
0.2319
4
-0.445
0.5211
-0.2319
-0.5211
-0.4179
0.4179
0.2319
0.5211
45
-1.247
0.4179
0.2319
0.2319
0.2319
-0.5211
0.4179
-1.802
-0.4179
0.5211
-0.5211
0.4179
-0.2319
Transcribed Image Text:The compound shown below includes a conjugated r-system. a) Ose the table to draw qualitative pictures off all Hückel MO's and calculate the total electron energy of the molecule. H H. D O,N D *- Orbital: c1 c2 03 04 c5 1.802 0.2319 0.4179 0.5211 0.5211 0.4179 0.2319 42 1.247 0.4179 0.5211 0.2319 0.5211 0.4179 -0.2319 43 0.445 0.5211 0.2319 -0.4179 -0.4179 0.5211 0.2319 4 -0.445 0.5211 -0.2319 -0.5211 -0.4179 0.4179 0.2319 0.5211 45 -1.247 0.4179 0.2319 0.2319 0.2319 -0.5211 0.4179 -1.802 -0.4179 0.5211 -0.5211 0.4179 -0.2319
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