There are two steps in the usual industrial preparation of acrylic acid, the immediate precursor of several useful plastics. In the first step, calcium carbide and water react to form acetylene and calcium hydroxide: CaC2(s) + 2 H2O(g) → C„H,(9) + Ca(OH)2(s) AH=-414. kJ In the second step, acetylene, carbon dioxide and water react to form acrylic acid: 6C,H2(9) + 3 CO2(9) + 4 H2O(9) → 5 CH,CHCO,H(9) AH=132. kJ Calculate the net change in enthalpy for the formation of one mole of acrylic acid from calcium carbide, water and carbon dioxide from these reactions. Round your answer to the nearest kJ.

There are two steps in the usual industrial preparation of acrylic acid, the immediate precursor of several useful plastics. In the first step, calcium carbide and water react to form acetylene and calcium hydroxide: CaC2(s) + 2 H2O(g) → C„H,(9) + Ca(OH)2(s) AH=-414. kJ In the second step, acetylene, carbon dioxide and water react to form acrylic acid: 6C,H2(9) + 3 CO2(9) + 4 H2O(9) → 5 CH,CHCO,H(9) AH=132. kJ Calculate the net change in enthalpy for the formation of one mole of acrylic acid from calcium carbide, water and carbon dioxide from these reactions. Round your answer to the nearest kJ.

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

See similar textbooks

Similar questions

Consider the following reaction. (a) Is the reaction exothermic or endothermic? exothermic endothermic CH3OH(g) → CO(g) + 2 H₂(g) AH +90.7 kJ (b) Calculate the amount of heat transferred when 35.0 g of CH3OH(g) are decomposed by this reaction at constant pressure. ΔΗ= 100.8 (c) If the enthalpy change is 19.0 kJ, how many grams of hydrogen gas are produced? 0.42 x g (d) How many kilojoules of heat are released when 13.0 g of CO(g) reacts completely with H₂(g) to form CH₂OH(g) at constant pressure? AH = -90.7 X kJ (e) Calculate AE when 400.0 g of CH3OH(g) completely reacts at a constant temperature of 300 K and constant pressure of 0.95 atm. R = 8.314 J/mol*K and R = 0.08206 atm*L/mol K-41.7 XkJ HopHelpCh5N1
1) When HCl(aq) and NaOH(aq) are mixed in a beaker, the beaker feels warm to the touch. What is known about the enthalpy of this reaction? The reaction is exothermic. ΔH is positive. The reaction is endothermic. Heat is absorbed from the surroundings. 2) Consider this combination reaction:2Mg(s)+O2(g)→2MgO(s) ΔH=−1204 kJ What is the enthalpy for the decomposition of 1 mole of MgO(s) into Mg(s) and O2(g)? -602 kJ/mol 602 kJ/mol -1204 kJ/mol 1204 kJ/mol 3) The enthalpy for the formation of 1 mole of NH3(aq) is -80.29 kJ/mol. What is the enthapy for the formation of 3 moles of NH3(aq)? -240.87 kJ −518×103 kJ -26.76 kJ -83.29 kJ
2. A small immersion heater was used to heat water in an insulated cup. The heater was placed in 100.0 g of distilled water initially at 21.0°C, and turned on for 60.0 seconds while the water was stirred with a thermometer. The final temperature of the water was measured to be 37.5°C. Assume the specific heat capacity of the water is 4.18 J/g °C. (a) Calculate the total heat energy in joules absorbed by the water and the average power in watts (1 watt = 1 joule/s) delivered by the heater. The heater was used to deliver 3000 joules of energy to 100.0 g of methanol (CH,OH(E)) in the same manner. The temperature of the methanol increased by 11.8 Celsius degrees. (b) Calculate the specific heat capacity of the methanol liquid. (c) (i) Calculate the mass of water (H,O, Co= 4.181 Jgl °C-) at 20.0°C that would be requireć %3D to cool a 30.0-g block of copper (Cu, co0.385 J gl °C-l) from 50.0°C to 25.0°C in an insulated cup. %3D (ii) Which liquid, water or methanol, would be more effective as…
The reaction between sodium metal and chlorine gas produces 822 kJ of heat energy for every chlorine molecule consumed [2 Na(s) + Cl2(g) → 2 NaCI(s)]. How much heat is released (in kJ) if 4.785 g of Na are consumed in the reaction?
48.2 mL of a solution of HCl is combined with 110.7 mL of 1.35 M NaOH in a calorimeter. The reaction mixture is initially at 22.4°C, and the final temperature after reaction is 29.3°C. What is the molarity of the HCl solution? You may assume that there is an excess of base (so that all the HCI has reacted), that the specific heat of the reaction mixture is 0.96 cal/g °C, and that the density of the reaction mixture is 1.02 g/mL. The heat of neutralization of HCl and NaOH is 13.6 kcal/mole.
The reaction between HCl and NaOH is represented below. When equal volumes of 1.00 M NaOH and 1.00 M HCl are mixed, 57.1 kJ of heat is released. What would A H be if 2.00 M HCI and 2.00 M NaOH is used instead of 1.00 M? HCl(aq) + NaOH(aq) → NaCl(aq) + H₂O(l) AH = -57.1 kJ/mol... (A) - 28.6 kJ B-85.7 kJ (c) -57.1 kJ D - 114 kJ
Charcoal is primarily carbon. What mass of CO2 is produced if you burn enough carbon (in the form of charcoal) to produce 4.80 x 10² kJ of heat? The balanced chemical equation is as follows: C(s) + O2 (g) → CO2 (g), Express the mass in grams to three significant figures. VE ΑΣΦ m = ? g AHxn=-393.5 kJ
In a popular television series, the two characters use thermite to assist with breaking into a chemical storage facility because the reaction between aluminum and iron(III) oxide produces a tremendous amount of heat. If they began with 10.0 g of Al, how many kJ of heat would be released? 29. 2 Al(s) + Fe,O3(s) → Al,O;(s) + 2 Fe(s) AH = -852 kJ 158 kJ A) B) 236 kJ 472 kJ D) None of the above
When 6.54 grams of Zn is placed in 500.0 mL of 1.00 M CuSO4(aq) in a coffee cup calorimeter, it reacts completely to displace copper. The temperature of the solution rises from 20.0˚C to 30.4˚C. Assume the coffee cup itself gains no heat and that the solution has the same density (1.00 g/mL) and specific heat (4.184 J/g˚C) as pure water. (a) How much heat does the solution gain during this reaction? (in J)
In a coffee-cup calorimeter, 59.0 mL of 0.100 M AgNO3 and 59.0 mL of 0.100 M HCI are mixed to yield the following reaction. Ag (aq) + Cl(aq) → AgCl(s) The two solutions were initially at 19.10°C, and the final temperature is 19.90°C. Calculate the heat that accompanies this reaction in kJ/mol of AgCl formed. Assume that the combined solution has a mass of 118.0 g and has a specific heat capacity of 4.18 1/°C 9- 407 kJ/mol
4. When 1.00 L of 1.05 M Ba(NO3)2 solution is mixed with 1.00 L of 1.10 M NazSO4 solution at 25.0°C in a coffee-cup calorimeter. The reaction is Ba(NOs)2(aq) + NazSO4(aq) → BaSO4(s) + 2NANO:(aq). The final temperature of the mixture increases to 28.1°C. Calculate the enthalpy change per mole for this process. (Assuming C=4.18 J °C' g' and density of the final solution is 1.05 g/ml).
Phosphoric acid, which is commonly used as rust inhibitor, food additive and etching agent for dental and orthopedic use, can be synthesized using a two-step thermal process. In the first step, phosphorus and oxygen react to form diphosphorus pentoxide: P4(1)+5 0,(g) 2 P,05(g) In the second step, diphosphorus pentoxide and water react to form phosphoric acid: P,0,(g)+3 H,O(1)→2 H,PO,(1) Write the net chemical equation for the production of phosphoric acid from phosphorus, oxygen and water. Be sure your equation is balanced.