Homework Help is Here – Start Your Trial Now!
Science
Chemistry
The

The

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
See similar textbooks
icon
Related questions
Question
100%

The second page is an example how it suppose to be done.

(Hex-4-en-3-one+CH3CH2MgBR). It's complete. Please follow directions. 

CH3 -CH 2CH=cH-CHz z. hex-4-en-3-one + CH3CH2MgBr 1. React the carbonyl compound: It is (circle one) CONJUGATED NON-CONJUGATED CH- CH2 The Nucleophile is CH3- CH = ě - cH = CH;-CHts Resonance System Option 1: Only the Nu created from RMgBr, NaBH or LIAIH, sticks R R-CH CH 8+ Option 2 All other Nu end up here eventually 1 (Preferred) NUB CHg-CH, (option 1 is react the electron-rich nucleophile with the electron- deficient carbonyl carbon) (option 2 is to react the electron-rich nucleophile with the slightly electron-deficient carbon at the end of the resonance system.) Circle the option and reason for reacting with a particular site of the carbonyl compound Option 1: RMgBr, LIAIH4, or NaBH4 Option 2: All other Nu end up sticking here 2. Take care of the negative formal charge of the oxygen in the tetrahedral complex :0:a Ht - CH-CH-CH3 CH2-CH3 Option 1 (Prefered). All cases except Option 2 1 (Preferred) Option 2: If there are no leaving groups, or if the only potential leaving group is the Nu that was just added and it is not a very good leaving group (N or O). (option 1 is reform the double bond) (option 2 is add a hydrogen ion) Circle the option and reason Option 1: Always use UNLESS * if u reform the DOuble bond you Option 2: There is no leaving group (there are whots tle Reason? carbons and hydrogens), OR there are only carbons and hydrogens except for the Nu that Ew A/ ReaSonae? - LeGuing group? - Shells ? elec trinegativity? just added, AND it is N or O. | charge 3. Check to see if the reaction continues (xs Nu, or C with 4 single bonds, 2 electron-withdrawing atoms with non-bonded electron pairs.)
Transcribed Image Text:CH3 -CH 2CH=cH-CHz z. hex-4-en-3-one + CH3CH2MgBr 1. React the carbonyl compound: It is (circle one) CONJUGATED NON-CONJUGATED CH- CH2 The Nucleophile is CH3- CH = ě - cH = CH;-CHts Resonance System Option 1: Only the Nu created from RMgBr, NaBH or LIAIH, sticks R R-CH CH 8+ Option 2 All other Nu end up here eventually 1 (Preferred) NUB CHg-CH, (option 1 is react the electron-rich nucleophile with the electron- deficient carbonyl carbon) (option 2 is to react the electron-rich nucleophile with the slightly electron-deficient carbon at the end of the resonance system.) Circle the option and reason for reacting with a particular site of the carbonyl compound Option 1: RMgBr, LIAIH4, or NaBH4 Option 2: All other Nu end up sticking here 2. Take care of the negative formal charge of the oxygen in the tetrahedral complex :0:a Ht - CH-CH-CH3 CH2-CH3 Option 1 (Prefered). All cases except Option 2 1 (Preferred) Option 2: If there are no leaving groups, or if the only potential leaving group is the Nu that was just added and it is not a very good leaving group (N or O). (option 1 is reform the double bond) (option 2 is add a hydrogen ion) Circle the option and reason Option 1: Always use UNLESS * if u reform the DOuble bond you Option 2: There is no leaving group (there are whots tle Reason? carbons and hydrogens), OR there are only carbons and hydrogens except for the Nu that Ew A/ ReaSonae? - LeGuing group? - Shells ? elec trinegativity? just added, AND it is N or O. | charge 3. Check to see if the reaction continues (xs Nu, or C with 4 single bonds, 2 electron-withdrawing atoms with non-bonded electron pairs.)
dd. cyclohexanone + 2 equivalents of ethanol 1. React the carbonyl compound: It is (circle one) CONJUGATED NON-CONJUGATED The Nucleophile is Potential to Establish a Resonance System Option 1: Almost all reactions Option 2: When Nu is a strong base ( OH or OR), and the leaving group is identical to the Nu 1 Preferred) (option 1 is react the electron-rich nucleophile with the electron- deficient carbonyl carbon) (option 2 is remove the alpha hydrogen and create a resonance-stabilized carbanion that can act as a nucleophile.) Circle the option and reason for reacting with a particular site of the carbonyl compound Option 1: Always use UNLESS Option 2: The Nu matches Y AND is -OR 2. Take care of the negative formal charge of the oxygen in the tetrahedral complex Option 1 (Preferred): All cases except Option 2 1 (Preferred) Option 2: If there are no leaving groups, R or if the only potential leaving group is the Nu that was just added and it is not a very good leaving group (N or O). (option 1 is reform the double bond) (option 2 is add a hydrogen ion) Circle the option and reason Option 1: Always use UNLESS Option 2: There is no leaving group (there are carbons and hydrogens), OR there are only carbons and hydrogens except for the Nu that just added, AND it is N or O. 3. Check to see if the reaction continues (xs Nu, or C with 4 single bonds, 2 electron-withdrawing atoms with non-bonded electron pairs.)
Transcribed Image Text:dd. cyclohexanone + 2 equivalents of ethanol 1. React the carbonyl compound: It is (circle one) CONJUGATED NON-CONJUGATED The Nucleophile is Potential to Establish a Resonance System Option 1: Almost all reactions Option 2: When Nu is a strong base ( OH or OR), and the leaving group is identical to the Nu 1 Preferred) (option 1 is react the electron-rich nucleophile with the electron- deficient carbonyl carbon) (option 2 is remove the alpha hydrogen and create a resonance-stabilized carbanion that can act as a nucleophile.) Circle the option and reason for reacting with a particular site of the carbonyl compound Option 1: Always use UNLESS Option 2: The Nu matches Y AND is -OR 2. Take care of the negative formal charge of the oxygen in the tetrahedral complex Option 1 (Preferred): All cases except Option 2 1 (Preferred) Option 2: If there are no leaving groups, R or if the only potential leaving group is the Nu that was just added and it is not a very good leaving group (N or O). (option 1 is reform the double bond) (option 2 is add a hydrogen ion) Circle the option and reason Option 1: Always use UNLESS Option 2: There is no leaving group (there are carbons and hydrogens), OR there are only carbons and hydrogens except for the Nu that just added, AND it is N or O. 3. Check to see if the reaction continues (xs Nu, or C with 4 single bonds, 2 electron-withdrawing atoms with non-bonded electron pairs.)
Expert Solution
steps

Step by step

Solved in 2 steps with 1 images

SEE SOLUTIONCheck out a sample Q&A here
Blurred answer
Knowledge Booster
Alkanes and Cycloalkanes
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY
SEE MORE TEXTBOOKS