The voltammogram below is recorded at a Au RDE (area 0.2 cm², rotation rate 3600 rpm) for a solution containing 100 mM Ce4+ + 50 mM Ce³+ in 3 M CH3SO3H in H₂O. 0.04 0.02 0.00 -0.02 - -0.04- I/MA -500 (1) 0 (2) 500 1000 (3) (4) (5) 1500 E vs SCE/mV

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Chapter1: Chemical Foundations
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The voltammogram below is recorded at a Au RDE (area 0.2 cm?, rotation rate 3600 rpm) for
a solution containing 100 mM Ce* + 50 mM Ce³3+ in 3 M CH3SO3H in H2O.
I/mA
0.04
(5)
0.02
(4)
0.00
-500
500
1000
1500
E vs SCE/mV
(3)
-0.02
(2)
-0.04
(1)
(a) Identify all the electrode reaction taking place (1–5) and indicate the rate-determining steps.
(Use the 'electrochemical series'.)
Transcribed Image Text:The voltammogram below is recorded at a Au RDE (area 0.2 cm?, rotation rate 3600 rpm) for a solution containing 100 mM Ce* + 50 mM Ce³3+ in 3 M CH3SO3H in H2O. I/mA 0.04 (5) 0.02 (4) 0.00 -500 500 1000 1500 E vs SCE/mV (3) -0.02 (2) -0.04 (1) (a) Identify all the electrode reaction taking place (1–5) and indicate the rate-determining steps. (Use the 'electrochemical series'.)
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