The vibrational levels of 23Na127I lie at the wavenumbers 142.81, 427.31, 710.31, and 991.81 cm−1. Show that they fit the expression (v + 1/2) ᷉v − (v + 1/2) 2xe ᷉v, and deduce the force constant, zero-point energy, and dissociation energy of the molecule.
Electronic Transitions and Spectroscopy
The term “electronic” connotes electron, and the term “transition” implies transformation. In a molecule, the electrons move from a lower to a higher energy state due to excitation. The two energy states, the ground state and the excited state are the lowest and the highest energy states, respectively. An energy change is observed with this transition, which depicts the various data related to the molecule.
Photoelectron Spectroscopy
Photoelectron spectroscopy (PES) is a part of experimental chemistry. It is a technique used in laboratories that involves projecting intense beams of radiation on a sample element. In response, the element ejects electrons for which the relative energies are measured.
The vibrational levels of 23Na127I lie at the wavenumbers 142.81, 427.31, 710.31, and 991.81 cm−1. Show that they fit the expression (v + 1/2) ᷉v − (v + 1/2) 2xe ᷉v, and deduce the force constant, zero-point energy, and dissociation energy of the molecule.
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