P11C.9 Provided higher order terms are neglected, eqn 11C.9b for the vibrational wavenumbers of an anharmonic oscillator, e AĞv+1/2 = Ỹ −2(v +1)x¸ỹ+…, is the equation of a straight line when the left- hand side is plotted against v + 1. Use the following data on CO to determine the values of ỹ and x¸ỹ for CO: V AĞ+1/2/cm-¹ 0 1 2143.1 2116.1 2 3 2088.9 2061.3 2033.5

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P11C.9 Provided higher order terms are neglected, eqn 11C.9b
for the vibrational wavenumbers of an anharmonic oscillator,
AĞv+1/2 = Ỹ −2(v +1)x¸ỹ+…, is the equation of a straight line when the left-
hand side is plotted against v + 1. Use the following data on CO to determine
the values of ỹ and x¸v for CO:
e
V
AĞ
[v+1/2/cm-¹
1
2143.1 2116.1
0
2
2088.9
3
2061.3
4
2033.5
Transcribed Image Text:P11C.9 Provided higher order terms are neglected, eqn 11C.9b for the vibrational wavenumbers of an anharmonic oscillator, AĞv+1/2 = Ỹ −2(v +1)x¸ỹ+…, is the equation of a straight line when the left- hand side is plotted against v + 1. Use the following data on CO to determine the values of ỹ and x¸v for CO: e V AĞ [v+1/2/cm-¹ 1 2143.1 2116.1 0 2 2088.9 3 2061.3 4 2033.5
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